Conformational Memory in Enantioselective Radical Reductions and a New Radical Clock Reaction

The radical decarboxylation of acid 1 led to tetrahydropyran 3 with significant optical activity. This transfer of chirality is an example of a conformational memory effect and derives from the slow ring inversion of the atropisomer 2 and its enantiomer 2‘. A similar conformational memory effect was...

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Veröffentlicht in:	Journal of the American Chemical Society 2000-10, Vol.122 (39), p.9386-9390
Hauptverfasser:	Buckmelter, Alexandre J, Kim, Angie I, Rychnovsky, Scott D
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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