Vibrationally excited carbon dioxide produced by infrared multiphoton pyrolysis

Vibrationally excited CO/sub 2/ has been observed in the infrared multiphoton pyrolysis (IRMP) of some organic molecules. The pyrolysis was induced by a high-power, pulsed CO/sub 2/ TEA laser. The vibrational excitation of CO/sub 2/ was investigated by time-delayed, intracavity probing with a weak f...

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Veröffentlicht in:	J. Phys. Chem.; (United States) 1984-06, Vol.88 (13), p.2817-2821
Hauptverfasser:	Colberg, Mark R, Watkins, Richard J, Krogh, Ole D
Format:	Artikel
Sprache:	eng
Schlagworte:	Atomic and molecular physics CARBON COMPOUNDS CARBON DIOXIDE CARBON DIOXIDE LASERS CARBON OXIDES CARBOXYLIC ACIDS CHALCOGENIDES CHEMICAL REACTION YIELD CHEMICAL REACTIONS DATA DECARBOXYLATION DECOMPOSITION DYNAMICS ELECTROMAGNETIC RADIATION ENERGY-LEVEL TRANSITIONS ESTERS Exact sciences and technology EXCITATION EXPERIMENTAL DATA GAS LASERS HETEROCYCLIC COMPOUNDS INFORMATION INFRARED RADIATION INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY KETO ACIDS LACTONES LASER RADIATION LASERS MECHANICS Molecular properties and interactions with photons NUMERICAL DATA ORGANIC ACIDS ORGANIC COMPOUNDS OXIDES OXYGEN COMPOUNDS PHOTOCHEMICAL REACTIONS PHOTOLYSIS Photon interactions with molecules Physics PYROLYSIS PYRUVIC ACID RADIATIONS THERMOCHEMICAL PROCESSES YIELDS 400500 > Photochemistry
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