Intracrystalline site preference of hydrogen isotopes in the water of crystallization of copper sulfate pentahydrate

Difference in the isotopic partition at different sites of the water of crystallization of CuSO/sub 4/.5H/sub 2/O (the site preference) was estimated for the hydrogen isotopes. Fractional dehydration of CuSO/sub 4/.5H/sub 2/O under vacuum at 0 and 25/sup 0/C was used to determine the isotopic ratio,...

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Veröffentlicht in:	J. Phys. Chem.; (United States) 1981-04, Vol.85 (7), p.792-797
Hauptverfasser:	Kita, Itsuro, Matsuo, Sadao
Format:	Artikel
Sprache:	eng
Schlagworte:	400202 - Isotope Effects, Isotope Exchange, & Isotope Separation COPPER COMPOUNDS COPPER SULFATES DEHYDRATION DEUTERIUM HYDRATES HYDROGEN ISOTOPES INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY ISOTOPE EFFECTS ISOTOPES LIGHT NUCLEI NUCLEI ODD-ODD NUCLEI OXYGEN COMPOUNDS STABLE ISOTOPES SULFATES SULFUR COMPOUNDS TRANSITION ELEMENT COMPOUNDS
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