Electron spin resonance study of the generation of stable arene radical cations in molten antimony trichloride
Pure molten antimony trichloride has been found to act as an oxidizing agent toward polycyclic arenes, producing stable solutions of radical cations. The oxidizing power of the Sb/sup 3 +//Sb/sup 0/ couple has been shown to be considerably increased or decreased by the addition, respectively, of a f...
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| Veröffentlicht in: | J. Phys. Chem.; (United States) 1980-02, Vol.84 (4), p.423-427 |
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| container_title | J. Phys. Chem.; (United States) |
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| creator | Buchanan, A. C Livingston, R Dworkin, A. S Smith, G. P |
| description | Pure molten antimony trichloride has been found to act as an oxidizing agent toward polycyclic arenes, producing stable solutions of radical cations. The oxidizing power of the Sb/sup 3 +//Sb/sup 0/ couple has been shown to be considerably increased or decreased by the addition, respectively, of a few mole percent of a chloride ion acceptor (AlCl/sub 3/) or donor (Me/sub 4/NCl). ESR spectra and coupling constants are reported for several arene radical cations in this medium, including those for the previously unreported acenaphthene radical cation. |
| doi_str_mv | 10.1021/j100441a016 |
| format | Article |
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ESR spectra and coupling constants are reported for several arene radical cations in this medium, including those for the previously unreported acenaphthene radical cation.</description><subject>01 COAL, LIGNITE, AND PEAT</subject><subject>010406 - Coal & Coal Products- Pyrolysis & Cracking- (-1987)</subject><subject>400301 - Organic Chemistry- Chemical & Physicochemical Properties- (-1987)</subject><subject>ANTIMONY CHLORIDES</subject><subject>ANTIMONY COMPOUNDS</subject><subject>AROMATICS</subject><subject>CATALYTIC EFFECTS</subject><subject>CHEMICAL REACTIONS</subject><subject>CHLORIDES</subject><subject>CHLORINE COMPOUNDS</subject><subject>COUPLING CONSTANTS</subject><subject>CRACKING</subject><subject>DATA</subject><subject>DATA FORMS</subject><subject>DECOMPOSITION</subject><subject>ELECTRON SPIN RESONANCE</subject><subject>EXPERIMENTAL DATA</subject><subject>HALIDES</subject><subject>HALOGEN COMPOUNDS</subject><subject>HYDROCRACKING</subject><subject>INFORMATION</subject><subject>INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY</subject><subject>ISOLATED VALUES</subject><subject>MAGNETIC RESONANCE</subject><subject>NUMERICAL DATA</subject><subject>ORGANIC COMPOUNDS</subject><subject>PYROLYSIS</subject><subject>RESONANCE</subject><subject>SPECTRA</subject><subject>THERMOCHEMICAL PROCESSES</subject><issn>0022-3654</issn><issn>1541-5740</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1980</creationdate><recordtype>article</recordtype><recordid>eNpt0E1LAzEQBuAgCtaPk38gePEgq8km2a5HlfpFQbEVj2GazNrUbSJJBPvvjVbEg6eBmYeXmSHkgLMTzmp-uuCMScmB8WaDDLiSvFJDyTbJgLG6rkSj5DbZSWnBGONC8AHxox5NjsHT9OY8jZiCB2-QpvxuVzR0NM-RvqDHCNkVVjopw6xHCrF0aQTrDPTUfI8TLSHL0Gf0FHx2y-BXNEdn5n2IzuIe2eqgT7j_U3fJ09VoenlTje-vby_PxxWIM5krACk76JpWdTCzKIyQbVm5bVtuOXZczeoZKgnKGhRtbRrZMI4WhzVvhK2t2CWH69yQstPJuIxmboL35VitaiWUEgUdr5GJIaWInX6LbglxpTnTX__Uf_5ZdLXWLmX8-KUQX3UzFEOlpw8TffU4GV_cnTH9XPzR2oNJehHeoy8H_5v8Ca-HhQI</recordid><startdate>198002</startdate><enddate>198002</enddate><creator>Buchanan, A. 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C</creatorcontrib><creatorcontrib>Livingston, R</creatorcontrib><creatorcontrib>Dworkin, A. S</creatorcontrib><creatorcontrib>Smith, G. P</creatorcontrib><creatorcontrib>Oak Ridge National Lab., TN</creatorcontrib><collection>Istex</collection><collection>CrossRef</collection><collection>OSTI.GOV</collection><jtitle>J. Phys. Chem.; (United States)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Buchanan, A. C</au><au>Livingston, R</au><au>Dworkin, A. S</au><au>Smith, G. P</au><aucorp>Oak Ridge National Lab., TN</aucorp><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Electron spin resonance study of the generation of stable arene radical cations in molten antimony trichloride</atitle><jtitle>J. Phys. Chem.; (United States)</jtitle><addtitle>J. Phys. Chem</addtitle><date>1980-02</date><risdate>1980</risdate><volume>84</volume><issue>4</issue><spage>423</spage><epage>427</epage><pages>423-427</pages><issn>0022-3654</issn><eissn>1541-5740</eissn><abstract>Pure molten antimony trichloride has been found to act as an oxidizing agent toward polycyclic arenes, producing stable solutions of radical cations. The oxidizing power of the Sb/sup 3 +//Sb/sup 0/ couple has been shown to be considerably increased or decreased by the addition, respectively, of a few mole percent of a chloride ion acceptor (AlCl/sub 3/) or donor (Me/sub 4/NCl). ESR spectra and coupling constants are reported for several arene radical cations in this medium, including those for the previously unreported acenaphthene radical cation.</abstract><cop>United States</cop><pub>American Chemical Society</pub><doi>10.1021/j100441a016</doi><tpages>5</tpages></addata></record> |
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| identifier | ISSN: 0022-3654 |
| ispartof | J. Phys. Chem.; (United States), 1980-02, Vol.84 (4), p.423-427 |
| issn | 0022-3654 1541-5740 |
| language | eng |
| recordid | cdi_crossref_primary_10_1021_j100441a016 |
| source | ACS Publications |
| subjects | 01 COAL, LIGNITE, AND PEAT 010406 - Coal & Coal Products- Pyrolysis & Cracking- (-1987) 400301 - Organic Chemistry- Chemical & Physicochemical Properties- (-1987) ANTIMONY CHLORIDES ANTIMONY COMPOUNDS AROMATICS CATALYTIC EFFECTS CHEMICAL REACTIONS CHLORIDES CHLORINE COMPOUNDS COUPLING CONSTANTS CRACKING DATA DATA FORMS DECOMPOSITION ELECTRON SPIN RESONANCE EXPERIMENTAL DATA HALIDES HALOGEN COMPOUNDS HYDROCRACKING INFORMATION INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY ISOLATED VALUES MAGNETIC RESONANCE NUMERICAL DATA ORGANIC COMPOUNDS PYROLYSIS RESONANCE SPECTRA THERMOCHEMICAL PROCESSES |
| title | Electron spin resonance study of the generation of stable arene radical cations in molten antimony trichloride |
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