Anomalous temperature-dependent reorientation of cresyl violet in 1-dodecanol

The temperature dependence of the dynamical behavior of cresyl violet in 1-dodecanol was studied by both microscopic and bulk physical techniques. Picosecond rotational diffusion measurements indicate that the solute experiences a very sharp temperature-dependent change in its environment. Steady-st...

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Veröffentlicht in:	J. Phys. Chem.; (United States) 1986-05, Vol.90 (11), p.2521-2525
Hauptverfasser:	Blanchard, G. J, Wirth, M. J
Format:	Artikel
Sprache:	eng
Schlagworte:	400301 - Organic Chemistry- Chemical & Physicochemical Properties- (-1987) ALCOHOLS AROMATICS Atomic and molecular physics CARBON 13 CARBON ISOTOPES CRESOLS DATA DIFFUSION EVEN-ODD NUCLEI Exact sciences and technology EXPERIMENTAL DATA HYDROXY COMPOUNDS INFORMATION INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY ISOTOPES LIGHT NUCLEI MAGNETIC RESONANCE Molecular properties and interactions with photons NUCLEAR MAGNETIC RESONANCE Nuclear resonance and relaxation NUCLEI NUMERICAL DATA ORGANIC COMPOUNDS PHENOLS Physics RELAXATION RESONANCE SOLVATION SPIN-LATTICE RELAXATION STABLE ISOTOPES TEMPERATURE DEPENDENCE
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