Anomalous temperature-dependent reorientation of cresyl violet in 1-dodecanol
The temperature dependence of the dynamical behavior of cresyl violet in 1-dodecanol was studied by both microscopic and bulk physical techniques. Picosecond rotational diffusion measurements indicate that the solute experiences a very sharp temperature-dependent change in its environment. Steady-st...
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| Veröffentlicht in: | J. Phys. Chem.; (United States) 1986-05, Vol.90 (11), p.2521-2525 |
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| container_issue | 11 |
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| container_title | J. Phys. Chem.; (United States) |
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| creator | Blanchard, G. J Wirth, M. J |
| description | The temperature dependence of the dynamical behavior of cresyl violet in 1-dodecanol was studied by both microscopic and bulk physical techniques. Picosecond rotational diffusion measurements indicate that the solute experiences a very sharp temperature-dependent change in its environment. Steady-state absorption spectroscopy reveals that this effect is due to a change in the solvent-solute interaction of cresyl violet. /sup 13/C NMR measurement of the temperature dependence of the solvent spin-lattice relaxation time (T/sub 1/) shows that the change in solvation is due to a previously unreported change in the state of the bulk solvent. |
| doi_str_mv | 10.1021/j100402a051 |
| format | Article |
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Steady-state absorption spectroscopy reveals that this effect is due to a change in the solvent-solute interaction of cresyl violet. /sup 13/C NMR measurement of the temperature dependence of the solvent spin-lattice relaxation time (T/sub 1/) shows that the change in solvation is due to a previously unreported change in the state of the bulk solvent.</description><identifier>ISSN: 0022-3654</identifier><identifier>EISSN: 1541-5740</identifier><identifier>DOI: 10.1021/j100402a051</identifier><identifier>CODEN: JPCHAX</identifier><language>eng</language><publisher>Washington, DC: American Chemical Society</publisher><subject>400301 - Organic Chemistry- Chemical & Physicochemical Properties- (-1987) ; ALCOHOLS ; AROMATICS ; Atomic and molecular physics ; CARBON 13 ; CARBON ISOTOPES ; CRESOLS ; DATA ; DIFFUSION ; EVEN-ODD NUCLEI ; Exact sciences and technology ; EXPERIMENTAL DATA ; HYDROXY COMPOUNDS ; INFORMATION ; INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY ; ISOTOPES ; LIGHT NUCLEI ; MAGNETIC RESONANCE ; Molecular properties and interactions with photons ; NUCLEAR MAGNETIC RESONANCE ; Nuclear resonance and relaxation ; NUCLEI ; NUMERICAL DATA ; ORGANIC COMPOUNDS ; PHENOLS ; Physics ; RELAXATION ; RESONANCE ; SOLVATION ; SPIN-LATTICE RELAXATION ; STABLE ISOTOPES ; TEMPERATURE DEPENDENCE</subject><ispartof>J. 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J</creatorcontrib><creatorcontrib>Wirth, M. J</creatorcontrib><creatorcontrib>Univ. of Wisconsin, Madison</creatorcontrib><title>Anomalous temperature-dependent reorientation of cresyl violet in 1-dodecanol</title><title>J. Phys. Chem.; (United States)</title><addtitle>J. Phys. Chem</addtitle><description>The temperature dependence of the dynamical behavior of cresyl violet in 1-dodecanol was studied by both microscopic and bulk physical techniques. Picosecond rotational diffusion measurements indicate that the solute experiences a very sharp temperature-dependent change in its environment. Steady-state absorption spectroscopy reveals that this effect is due to a change in the solvent-solute interaction of cresyl violet. /sup 13/C NMR measurement of the temperature dependence of the solvent spin-lattice relaxation time (T/sub 1/) shows that the change in solvation is due to a previously unreported change in the state of the bulk solvent.</description><subject>400301 - Organic Chemistry- Chemical & Physicochemical Properties- (-1987)</subject><subject>ALCOHOLS</subject><subject>AROMATICS</subject><subject>Atomic and molecular physics</subject><subject>CARBON 13</subject><subject>CARBON ISOTOPES</subject><subject>CRESOLS</subject><subject>DATA</subject><subject>DIFFUSION</subject><subject>EVEN-ODD NUCLEI</subject><subject>Exact sciences and technology</subject><subject>EXPERIMENTAL DATA</subject><subject>HYDROXY COMPOUNDS</subject><subject>INFORMATION</subject><subject>INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY</subject><subject>ISOTOPES</subject><subject>LIGHT NUCLEI</subject><subject>MAGNETIC RESONANCE</subject><subject>Molecular properties and interactions with photons</subject><subject>NUCLEAR MAGNETIC RESONANCE</subject><subject>Nuclear resonance and relaxation</subject><subject>NUCLEI</subject><subject>NUMERICAL DATA</subject><subject>ORGANIC COMPOUNDS</subject><subject>PHENOLS</subject><subject>Physics</subject><subject>RELAXATION</subject><subject>RESONANCE</subject><subject>SOLVATION</subject><subject>SPIN-LATTICE RELAXATION</subject><subject>STABLE ISOTOPES</subject><subject>TEMPERATURE DEPENDENCE</subject><issn>0022-3654</issn><issn>1541-5740</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1986</creationdate><recordtype>article</recordtype><recordid>eNpt0N9LHDEQB_AgFXrVPvUfWIrQB9k6STbJ7aM_qhUUxZ4c-BKy2QnNuZccSU7qf-_KivTBpxmYzwzDl5BvFH5SYPRoRQEaYAYE3SEzKhpaC9XAJzIDYKzmUjSfyZecVwBAOaczcn0c4toMcZurgusNJlO2CeseNxh6DKVKGJMfG1N8DFV0lU2Yn4fqyccBS-VDRes-9mhNiMM-2XVmyPj1re6R-_Nfi9Pf9dXNxeXp8VVtuFCl7ubOgutY2xnu5tBbKXvLOussbQWItmmRoxE9SAQGwipmEJyTnWBq7mjP98j36W7MxetsfUH718YQ0BYtZKuYkCM6nJBNMeeETm-SX5v0rCno17j0f3GN-mDSG5OtGVwywfr8vqJa2XKqRlZPzOeC_97HJj1qqbgSenH7Ry_h5Ky9Wz7o1yd-TN7YrFdxm8KYy4cPvACq-IW6</recordid><startdate>19860501</startdate><enddate>19860501</enddate><creator>Blanchard, G. J</creator><creator>Wirth, M. J</creator><general>American Chemical Society</general><scope>BSCLL</scope><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>OTOTI</scope></search><sort><creationdate>19860501</creationdate><title>Anomalous temperature-dependent reorientation of cresyl violet in 1-dodecanol</title><author>Blanchard, G. J ; Wirth, M. J</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a357t-b8fc0fb29ba3f80dc66dc2bcfc19505949e3ea5d06e0205c72ae0ff6b5278f1d3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1986</creationdate><topic>400301 - Organic Chemistry- Chemical & Physicochemical Properties- (-1987)</topic><topic>ALCOHOLS</topic><topic>AROMATICS</topic><topic>Atomic and molecular physics</topic><topic>CARBON 13</topic><topic>CARBON ISOTOPES</topic><topic>CRESOLS</topic><topic>DATA</topic><topic>DIFFUSION</topic><topic>EVEN-ODD NUCLEI</topic><topic>Exact sciences and technology</topic><topic>EXPERIMENTAL DATA</topic><topic>HYDROXY COMPOUNDS</topic><topic>INFORMATION</topic><topic>INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY</topic><topic>ISOTOPES</topic><topic>LIGHT NUCLEI</topic><topic>MAGNETIC RESONANCE</topic><topic>Molecular properties and interactions with photons</topic><topic>NUCLEAR MAGNETIC RESONANCE</topic><topic>Nuclear resonance and relaxation</topic><topic>NUCLEI</topic><topic>NUMERICAL DATA</topic><topic>ORGANIC COMPOUNDS</topic><topic>PHENOLS</topic><topic>Physics</topic><topic>RELAXATION</topic><topic>RESONANCE</topic><topic>SOLVATION</topic><topic>SPIN-LATTICE RELAXATION</topic><topic>STABLE ISOTOPES</topic><topic>TEMPERATURE DEPENDENCE</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Blanchard, G. J</creatorcontrib><creatorcontrib>Wirth, M. J</creatorcontrib><creatorcontrib>Univ. of Wisconsin, Madison</creatorcontrib><collection>Istex</collection><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>OSTI.GOV</collection><jtitle>J. Phys. Chem.; (United States)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Blanchard, G. J</au><au>Wirth, M. J</au><aucorp>Univ. of Wisconsin, Madison</aucorp><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Anomalous temperature-dependent reorientation of cresyl violet in 1-dodecanol</atitle><jtitle>J. Phys. Chem.; (United States)</jtitle><addtitle>J. Phys. Chem</addtitle><date>1986-05-01</date><risdate>1986</risdate><volume>90</volume><issue>11</issue><spage>2521</spage><epage>2525</epage><pages>2521-2525</pages><issn>0022-3654</issn><eissn>1541-5740</eissn><coden>JPCHAX</coden><abstract>The temperature dependence of the dynamical behavior of cresyl violet in 1-dodecanol was studied by both microscopic and bulk physical techniques. Picosecond rotational diffusion measurements indicate that the solute experiences a very sharp temperature-dependent change in its environment. Steady-state absorption spectroscopy reveals that this effect is due to a change in the solvent-solute interaction of cresyl violet. /sup 13/C NMR measurement of the temperature dependence of the solvent spin-lattice relaxation time (T/sub 1/) shows that the change in solvation is due to a previously unreported change in the state of the bulk solvent.</abstract><cop>Washington, DC</cop><pub>American Chemical Society</pub><doi>10.1021/j100402a051</doi><tpages>5</tpages></addata></record> |
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| identifier | ISSN: 0022-3654 |
| ispartof | J. Phys. Chem.; (United States), 1986-05, Vol.90 (11), p.2521-2525 |
| issn | 0022-3654 1541-5740 |
| language | eng |
| recordid | cdi_crossref_primary_10_1021_j100402a051 |
| source | American Chemical Society Journals |
| subjects | 400301 - Organic Chemistry- Chemical & Physicochemical Properties- (-1987) ALCOHOLS AROMATICS Atomic and molecular physics CARBON 13 CARBON ISOTOPES CRESOLS DATA DIFFUSION EVEN-ODD NUCLEI Exact sciences and technology EXPERIMENTAL DATA HYDROXY COMPOUNDS INFORMATION INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY ISOTOPES LIGHT NUCLEI MAGNETIC RESONANCE Molecular properties and interactions with photons NUCLEAR MAGNETIC RESONANCE Nuclear resonance and relaxation NUCLEI NUMERICAL DATA ORGANIC COMPOUNDS PHENOLS Physics RELAXATION RESONANCE SOLVATION SPIN-LATTICE RELAXATION STABLE ISOTOPES TEMPERATURE DEPENDENCE |
| title | Anomalous temperature-dependent reorientation of cresyl violet in 1-dodecanol |
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