Quantized colloids produced by dissolution of layered semiconductors in acetonitrile
Small collodial particles (10-35 A) of crystalline MoS/sub 2/ and WS/sub 2/ exhibiting size quantization effects in their optical absorption spectra are believed to form by simple dissolution of crystalline powder in acetonitrile. This conclusion is supported by electron microscopy, electron diffrac...
Gespeichert in:
| Veröffentlicht in: | J. Phys. Chem.; (United States) 1988-03, Vol.92 (6), p.1400-1402 |
|---|---|
| Hauptverfasser: | , , , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 1402 |
|---|---|
| container_issue | 6 |
| container_start_page | 1400 |
| container_title | J. Phys. Chem.; (United States) |
| container_volume | 92 |
| creator | Peterson, M. W Nenadovic, M. T Rajh, T Herak, R Micic, O. I Goral, J. P Nozik, A. J |
| description | Small collodial particles (10-35 A) of crystalline MoS/sub 2/ and WS/sub 2/ exhibiting size quantization effects in their optical absorption spectra are believed to form by simple dissolution of crystalline powder in acetonitrile. This conclusion is supported by electron microscopy, electron diffraction, X-ray diffraction, EDAX, and chemical analyses. The authors speculate that the MoS/sub 2/ and WS/sub 2/ clusters are formed by cleavage of the van der Waals layers by penetrating solvent molecules, a process related to the well-known formation of colloids from layered clay structures. Preliminary experiments with layered WSe/sub 2/ suggest that this material may also form colloids by a similar mechanism. |
| doi_str_mv | 10.1021/j100317a007 |
| format | Article |
| fullrecord | <record><control><sourceid>istex_osti_</sourceid><recordid>TN_cdi_crossref_primary_10_1021_j100317a007</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>ark_67375_TPS_PNLV8V0B_X</sourcerecordid><originalsourceid>FETCH-LOGICAL-a423t-f156dd4ccd1044634e8255f7cdc41ee0856e1cb866c988a1219a75b58d5069603</originalsourceid><addsrcrecordid>eNpt0E1LHEEQBuAmKGTVnPIHBgl4CBOrpj-m96hiNLD4QTaSW9Nb3UN6HaeX7l5w8-szMkE8eCqoeqooXsY-I3xDaPB0jQAcWwvQfmAzlAJr2QrYYzOApqm5kuIjO8h5DQDIOc7Y8n5rhxL-eldR7PsYXK42KbotjZ3VrnIh59hvS4hDFbuqtzufxkn2T4HiMLISU67CUFnyJQ6hpND7I7bf2T77T__rIfv1_XJ5cV0vbq9-XJwtaisaXuoOpXJOEDkEIRQXXjdSdi05Eug9aKk80korRXOtLTY4t61cSe0kqLkCfsiOp7sxl2AyheLpz_jW4KkYyUHpuRzR1wlRijkn35lNCk827QyCeUnNvElt1F8mvbGZbN8lO1DIryutFqDw5Wg9sZCLf34d2_RoVMtbaZZ3P83dzeJBP8C5-T36k8lbymYdt2kYc3n3gX9hhIeT</addsrcrecordid><sourcetype>Open Access Repository</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>Quantized colloids produced by dissolution of layered semiconductors in acetonitrile</title><source>ACS Journals</source><creator>Peterson, M. W ; Nenadovic, M. T ; Rajh, T ; Herak, R ; Micic, O. I ; Goral, J. P ; Nozik, A. J</creator><creatorcontrib>Peterson, M. W ; Nenadovic, M. T ; Rajh, T ; Herak, R ; Micic, O. I ; Goral, J. P ; Nozik, A. J ; Solar Energy Research Institute, Golden, CO (USA)</creatorcontrib><description>Small collodial particles (10-35 A) of crystalline MoS/sub 2/ and WS/sub 2/ exhibiting size quantization effects in their optical absorption spectra are believed to form by simple dissolution of crystalline powder in acetonitrile. This conclusion is supported by electron microscopy, electron diffraction, X-ray diffraction, EDAX, and chemical analyses. The authors speculate that the MoS/sub 2/ and WS/sub 2/ clusters are formed by cleavage of the van der Waals layers by penetrating solvent molecules, a process related to the well-known formation of colloids from layered clay structures. Preliminary experiments with layered WSe/sub 2/ suggest that this material may also form colloids by a similar mechanism.</description><identifier>ISSN: 0022-3654</identifier><identifier>EISSN: 1541-5740</identifier><identifier>DOI: 10.1021/j100317a007</identifier><identifier>CODEN: JPCHAX</identifier><language>eng</language><publisher>Washington, DC: American Chemical Society</publisher><subject>400201 - Chemical & Physicochemical Properties ; ABSORPTION SPECTROSCOPY ; ACETONITRILE ; CHALCOGENIDES ; CHEMICAL PREPARATION ; Chemistry ; Colloidal state and disperse state ; COLLOIDS ; CRYSTALS ; DISPERSIONS ; Exact sciences and technology ; General and physical chemistry ; INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY ; MOLYBDENUM COMPOUNDS ; MOLYBDENUM SULFIDES ; NITRILES ; ORGANIC COMPOUNDS ; ORGANIC NITROGEN COMPOUNDS ; PARTICLE SIZE ; Physical and chemical studies. Granulometry. Electrokinetic phenomena ; REFRACTORY METAL COMPOUNDS ; SIZE ; SOLID CLUSTERS ; SPECTROSCOPY ; SULFIDES ; SULFUR COMPOUNDS ; SYNTHESIS ; TRANSITION ELEMENT COMPOUNDS ; TUNGSTEN COMPOUNDS ; TUNGSTEN SULFIDES ; VAN DER WAALS FORCES</subject><ispartof>J. Phys. Chem.; (United States), 1988-03, Vol.92 (6), p.1400-1402</ispartof><rights>1988 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-a423t-f156dd4ccd1044634e8255f7cdc41ee0856e1cb866c988a1219a75b58d5069603</citedby></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://pubs.acs.org/doi/pdf/10.1021/j100317a007$$EPDF$$P50$$Gacs$$H</linktopdf><linktohtml>$$Uhttps://pubs.acs.org/doi/10.1021/j100317a007$$EHTML$$P50$$Gacs$$H</linktohtml><link.rule.ids>314,780,784,885,2763,27074,27922,27923,56736,56786</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=7840615$$DView record in Pascal Francis$$Hfree_for_read</backlink><backlink>$$Uhttps://www.osti.gov/biblio/5306895$$D View this record in Osti.gov$$Hfree_for_read</backlink></links><search><creatorcontrib>Peterson, M. W</creatorcontrib><creatorcontrib>Nenadovic, M. T</creatorcontrib><creatorcontrib>Rajh, T</creatorcontrib><creatorcontrib>Herak, R</creatorcontrib><creatorcontrib>Micic, O. I</creatorcontrib><creatorcontrib>Goral, J. P</creatorcontrib><creatorcontrib>Nozik, A. J</creatorcontrib><creatorcontrib>Solar Energy Research Institute, Golden, CO (USA)</creatorcontrib><title>Quantized colloids produced by dissolution of layered semiconductors in acetonitrile</title><title>J. Phys. Chem.; (United States)</title><addtitle>J. Phys. Chem</addtitle><description>Small collodial particles (10-35 A) of crystalline MoS/sub 2/ and WS/sub 2/ exhibiting size quantization effects in their optical absorption spectra are believed to form by simple dissolution of crystalline powder in acetonitrile. This conclusion is supported by electron microscopy, electron diffraction, X-ray diffraction, EDAX, and chemical analyses. The authors speculate that the MoS/sub 2/ and WS/sub 2/ clusters are formed by cleavage of the van der Waals layers by penetrating solvent molecules, a process related to the well-known formation of colloids from layered clay structures. Preliminary experiments with layered WSe/sub 2/ suggest that this material may also form colloids by a similar mechanism.</description><subject>400201 - Chemical & Physicochemical Properties</subject><subject>ABSORPTION SPECTROSCOPY</subject><subject>ACETONITRILE</subject><subject>CHALCOGENIDES</subject><subject>CHEMICAL PREPARATION</subject><subject>Chemistry</subject><subject>Colloidal state and disperse state</subject><subject>COLLOIDS</subject><subject>CRYSTALS</subject><subject>DISPERSIONS</subject><subject>Exact sciences and technology</subject><subject>General and physical chemistry</subject><subject>INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY</subject><subject>MOLYBDENUM COMPOUNDS</subject><subject>MOLYBDENUM SULFIDES</subject><subject>NITRILES</subject><subject>ORGANIC COMPOUNDS</subject><subject>ORGANIC NITROGEN COMPOUNDS</subject><subject>PARTICLE SIZE</subject><subject>Physical and chemical studies. Granulometry. Electrokinetic phenomena</subject><subject>REFRACTORY METAL COMPOUNDS</subject><subject>SIZE</subject><subject>SOLID CLUSTERS</subject><subject>SPECTROSCOPY</subject><subject>SULFIDES</subject><subject>SULFUR COMPOUNDS</subject><subject>SYNTHESIS</subject><subject>TRANSITION ELEMENT COMPOUNDS</subject><subject>TUNGSTEN COMPOUNDS</subject><subject>TUNGSTEN SULFIDES</subject><subject>VAN DER WAALS FORCES</subject><issn>0022-3654</issn><issn>1541-5740</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1988</creationdate><recordtype>article</recordtype><recordid>eNpt0E1LHEEQBuAmKGTVnPIHBgl4CBOrpj-m96hiNLD4QTaSW9Nb3UN6HaeX7l5w8-szMkE8eCqoeqooXsY-I3xDaPB0jQAcWwvQfmAzlAJr2QrYYzOApqm5kuIjO8h5DQDIOc7Y8n5rhxL-eldR7PsYXK42KbotjZ3VrnIh59hvS4hDFbuqtzufxkn2T4HiMLISU67CUFnyJQ6hpND7I7bf2T77T__rIfv1_XJ5cV0vbq9-XJwtaisaXuoOpXJOEDkEIRQXXjdSdi05Eug9aKk80korRXOtLTY4t61cSe0kqLkCfsiOp7sxl2AyheLpz_jW4KkYyUHpuRzR1wlRijkn35lNCk827QyCeUnNvElt1F8mvbGZbN8lO1DIryutFqDw5Wg9sZCLf34d2_RoVMtbaZZ3P83dzeJBP8C5-T36k8lbymYdt2kYc3n3gX9hhIeT</recordid><startdate>198803</startdate><enddate>198803</enddate><creator>Peterson, M. W</creator><creator>Nenadovic, M. T</creator><creator>Rajh, T</creator><creator>Herak, R</creator><creator>Micic, O. I</creator><creator>Goral, J. P</creator><creator>Nozik, A. J</creator><general>American Chemical Society</general><scope>BSCLL</scope><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>OTOTI</scope></search><sort><creationdate>198803</creationdate><title>Quantized colloids produced by dissolution of layered semiconductors in acetonitrile</title><author>Peterson, M. W ; Nenadovic, M. T ; Rajh, T ; Herak, R ; Micic, O. I ; Goral, J. P ; Nozik, A. J</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a423t-f156dd4ccd1044634e8255f7cdc41ee0856e1cb866c988a1219a75b58d5069603</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1988</creationdate><topic>400201 - Chemical & Physicochemical Properties</topic><topic>ABSORPTION SPECTROSCOPY</topic><topic>ACETONITRILE</topic><topic>CHALCOGENIDES</topic><topic>CHEMICAL PREPARATION</topic><topic>Chemistry</topic><topic>Colloidal state and disperse state</topic><topic>COLLOIDS</topic><topic>CRYSTALS</topic><topic>DISPERSIONS</topic><topic>Exact sciences and technology</topic><topic>General and physical chemistry</topic><topic>INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY</topic><topic>MOLYBDENUM COMPOUNDS</topic><topic>MOLYBDENUM SULFIDES</topic><topic>NITRILES</topic><topic>ORGANIC COMPOUNDS</topic><topic>ORGANIC NITROGEN COMPOUNDS</topic><topic>PARTICLE SIZE</topic><topic>Physical and chemical studies. Granulometry. Electrokinetic phenomena</topic><topic>REFRACTORY METAL COMPOUNDS</topic><topic>SIZE</topic><topic>SOLID CLUSTERS</topic><topic>SPECTROSCOPY</topic><topic>SULFIDES</topic><topic>SULFUR COMPOUNDS</topic><topic>SYNTHESIS</topic><topic>TRANSITION ELEMENT COMPOUNDS</topic><topic>TUNGSTEN COMPOUNDS</topic><topic>TUNGSTEN SULFIDES</topic><topic>VAN DER WAALS FORCES</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Peterson, M. W</creatorcontrib><creatorcontrib>Nenadovic, M. T</creatorcontrib><creatorcontrib>Rajh, T</creatorcontrib><creatorcontrib>Herak, R</creatorcontrib><creatorcontrib>Micic, O. I</creatorcontrib><creatorcontrib>Goral, J. P</creatorcontrib><creatorcontrib>Nozik, A. J</creatorcontrib><creatorcontrib>Solar Energy Research Institute, Golden, CO (USA)</creatorcontrib><collection>Istex</collection><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>OSTI.GOV</collection><jtitle>J. Phys. Chem.; (United States)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Peterson, M. W</au><au>Nenadovic, M. T</au><au>Rajh, T</au><au>Herak, R</au><au>Micic, O. I</au><au>Goral, J. P</au><au>Nozik, A. J</au><aucorp>Solar Energy Research Institute, Golden, CO (USA)</aucorp><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Quantized colloids produced by dissolution of layered semiconductors in acetonitrile</atitle><jtitle>J. Phys. Chem.; (United States)</jtitle><addtitle>J. Phys. Chem</addtitle><date>1988-03</date><risdate>1988</risdate><volume>92</volume><issue>6</issue><spage>1400</spage><epage>1402</epage><pages>1400-1402</pages><issn>0022-3654</issn><eissn>1541-5740</eissn><coden>JPCHAX</coden><abstract>Small collodial particles (10-35 A) of crystalline MoS/sub 2/ and WS/sub 2/ exhibiting size quantization effects in their optical absorption spectra are believed to form by simple dissolution of crystalline powder in acetonitrile. This conclusion is supported by electron microscopy, electron diffraction, X-ray diffraction, EDAX, and chemical analyses. The authors speculate that the MoS/sub 2/ and WS/sub 2/ clusters are formed by cleavage of the van der Waals layers by penetrating solvent molecules, a process related to the well-known formation of colloids from layered clay structures. Preliminary experiments with layered WSe/sub 2/ suggest that this material may also form colloids by a similar mechanism.</abstract><cop>Washington, DC</cop><pub>American Chemical Society</pub><doi>10.1021/j100317a007</doi><tpages>3</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0022-3654 |
| ispartof | J. Phys. Chem.; (United States), 1988-03, Vol.92 (6), p.1400-1402 |
| issn | 0022-3654 1541-5740 |
| language | eng |
| recordid | cdi_crossref_primary_10_1021_j100317a007 |
| source | ACS Journals |
| subjects | 400201 - Chemical & Physicochemical Properties ABSORPTION SPECTROSCOPY ACETONITRILE CHALCOGENIDES CHEMICAL PREPARATION Chemistry Colloidal state and disperse state COLLOIDS CRYSTALS DISPERSIONS Exact sciences and technology General and physical chemistry INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY MOLYBDENUM COMPOUNDS MOLYBDENUM SULFIDES NITRILES ORGANIC COMPOUNDS ORGANIC NITROGEN COMPOUNDS PARTICLE SIZE Physical and chemical studies. Granulometry. Electrokinetic phenomena REFRACTORY METAL COMPOUNDS SIZE SOLID CLUSTERS SPECTROSCOPY SULFIDES SULFUR COMPOUNDS SYNTHESIS TRANSITION ELEMENT COMPOUNDS TUNGSTEN COMPOUNDS TUNGSTEN SULFIDES VAN DER WAALS FORCES |
| title | Quantized colloids produced by dissolution of layered semiconductors in acetonitrile |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-14T16%3A46%3A26IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-istex_osti_&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Quantized%20colloids%20produced%20by%20dissolution%20of%20layered%20semiconductors%20in%20acetonitrile&rft.jtitle=J.%20Phys.%20Chem.;%20(United%20States)&rft.au=Peterson,%20M.%20W&rft.aucorp=Solar%20Energy%20Research%20Institute,%20Golden,%20CO%20(USA)&rft.date=1988-03&rft.volume=92&rft.issue=6&rft.spage=1400&rft.epage=1402&rft.pages=1400-1402&rft.issn=0022-3654&rft.eissn=1541-5740&rft.coden=JPCHAX&rft_id=info:doi/10.1021/j100317a007&rft_dat=%3Cistex_osti_%3Eark_67375_TPS_PNLV8V0B_X%3C/istex_osti_%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_id=info:pmid/&rfr_iscdi=true |