Transient storage of photochemically produced oxidative and reductive equivalents in soluble redox polymers

Optical excitation and electron-transfer quenching of the metal to ligand charge-transfer (MLCT) excited state(s) of ((5-NH/sub 2/-phen)Ru(bpy)/sub 2/)/sup 2 +/ occur in solutions containing polystyrene polymers in which either pendant paraquat (PQ/sup 2 +/) or phenothiazine (PTZ) sites are attached...

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Veröffentlicht in:	J. Phys. Chem.; (United States) 1986-02, Vol.90 (5), p.728-730
Hauptverfasser:	Margerum, Lawrence D, Murray, Royce W, Meyer, Thomas J
Format:	Artikel
Sprache:	eng
Schlagworte:	400500 - Photochemistry AMINES Applied sciences AZINES BIPYRIDINES CHEMICAL REACTIONS CHEMISTRY COMPLEXES DATA DECOMPOSITION ELECTRON TRANSFER Exact sciences and technology EXPERIMENTAL DATA HETEROCYCLIC COMPOUNDS INFORMATION INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY LIFETIME MATERIALS NUMERICAL DATA ORGANIC COMPOUNDS ORGANIC NITROGEN COMPOUNDS ORGANIC POLYMERS OXIDATION PETROCHEMICALS PETROLEUM PRODUCTS PHOTOCHEMICAL REACTIONS PHOTOCHEMISTRY PHOTOLYSIS Physicochemistry of polymers PLASTICS POLYMERS Polymers and radiations POLYOLEFINS POLYSTYRENE POLYVINYLS Properties and characterization PYRIDINES REDUCTION RUTHENIUM COMPLEXES SYNTHETIC MATERIALS TRANSITION ELEMENT COMPLEXES
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