Photochemistry of benzene and oxygen in supersonic cluster beams
A reaction is seen to occur between benzene and oxygen in a supersonic beam when mixed clusters are irradiated by 193nm. This reaction has been investigated by multiphoton ionization mass spectrometry, with primary reaction products including the introduction of up to four oxygen atoms onto the benz...
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| Veröffentlicht in: | J. Phys. Chem.; (United States) 1982-11, Vol.86 (23), p.4467-4469 |
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| container_end_page | 4469 |
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| container_issue | 23 |
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| container_title | J. Phys. Chem.; (United States) |
| container_volume | 86 |
| creator | Knee, J. L Otis, C. E Johnson, Philip M |
| description | A reaction is seen to occur between benzene and oxygen in a supersonic beam when mixed clusters are irradiated by 193nm. This reaction has been investigated by multiphoton ionization mass spectrometry, with primary reaction products including the introduction of up to four oxygen atoms onto the benzene, as well as species resulting from hydrogen abstraction. A two laser experiment indicates that the initial step in the photochemical reaction results in a neutral species which lives for longer than 100 ..mu..s. |
| doi_str_mv | 10.1021/j100220a002 |
| format | Article |
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L ; Otis, C. E ; Johnson, Philip M</creator><creatorcontrib>Knee, J. L ; Otis, C. E ; Johnson, Philip M ; State Univ. of New York, Stony Brook</creatorcontrib><description>A reaction is seen to occur between benzene and oxygen in a supersonic beam when mixed clusters are irradiated by 193nm. This reaction has been investigated by multiphoton ionization mass spectrometry, with primary reaction products including the introduction of up to four oxygen atoms onto the benzene, as well as species resulting from hydrogen abstraction. A two laser experiment indicates that the initial step in the photochemical reaction results in a neutral species which lives for longer than 100 ..mu..s.</description><identifier>ISSN: 0022-3654</identifier><identifier>EISSN: 1541-5740</identifier><identifier>DOI: 10.1021/j100220a002</identifier><language>eng</language><publisher>United States: American Chemical Society</publisher><subject>400500 - Photochemistry ; AIR TRANSPORT ; AROMATICS ; BEAMS ; BENZENE ; CHEMISTRY ; CLUSTER BEAMS ; ELEMENTS ; HYDROCARBONS ; INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY ; MASS SPECTRA ; NONMETALS ; ORGANIC COMPOUNDS ; OXYGEN ; PHOTOCHEMISTRY ; SPECTRA ; SUPERSONIC TRANSPORT ; TRANSPORT</subject><ispartof>J. Phys. 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E</creatorcontrib><creatorcontrib>Johnson, Philip M</creatorcontrib><creatorcontrib>State Univ. of New York, Stony Brook</creatorcontrib><title>Photochemistry of benzene and oxygen in supersonic cluster beams</title><title>J. Phys. Chem.; (United States)</title><addtitle>J. Phys. Chem</addtitle><description>A reaction is seen to occur between benzene and oxygen in a supersonic beam when mixed clusters are irradiated by 193nm. This reaction has been investigated by multiphoton ionization mass spectrometry, with primary reaction products including the introduction of up to four oxygen atoms onto the benzene, as well as species resulting from hydrogen abstraction. A two laser experiment indicates that the initial step in the photochemical reaction results in a neutral species which lives for longer than 100 ..mu..s.</description><subject>400500 - Photochemistry</subject><subject>AIR TRANSPORT</subject><subject>AROMATICS</subject><subject>BEAMS</subject><subject>BENZENE</subject><subject>CHEMISTRY</subject><subject>CLUSTER BEAMS</subject><subject>ELEMENTS</subject><subject>HYDROCARBONS</subject><subject>INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY</subject><subject>MASS SPECTRA</subject><subject>NONMETALS</subject><subject>ORGANIC COMPOUNDS</subject><subject>OXYGEN</subject><subject>PHOTOCHEMISTRY</subject><subject>SPECTRA</subject><subject>SUPERSONIC TRANSPORT</subject><subject>TRANSPORT</subject><issn>0022-3654</issn><issn>1541-5740</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1982</creationdate><recordtype>article</recordtype><recordid>eNptkE9LAzEQxYMoWKsnv8DixYOsZvJnd3NTirZCrRXrOWTTrN3aJpKk0PrpTVkRD8Iw8xh-PHgPoXPA14AJ3CwBY0KwSvsA9YAzyHnJ8CHq7f85LTg7RichLDHGQCn00O104aLTC7NuQ_S7zDVZbeyXsSZTdp657e7d2Ky1Wdh8Gh-cbXWmV5sQjU-gWodTdNSoVTBnP7eP3h7uZ4NRPn4ePg7uxrmipIp5BbwkqhaCV_NaMFE0Zk4NYUwLCjUnpOBNsdcEg-aN4rUggoESAJoqIWgfXXS-LsRWBt1GoxfaWWt0lAVjFU3TR1cdpL0LwZtGfvp2rfxOApb7huSfhhKdd3SKbra_qPIfsihpyeVs-iqHEz4YvTxVcpL4y45XOsil23ibAv_r_A0GbnJT</recordid><startdate>19821101</startdate><enddate>19821101</enddate><creator>Knee, J. L</creator><creator>Otis, C. E</creator><creator>Johnson, Philip M</creator><general>American Chemical Society</general><scope>BSCLL</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>OTOTI</scope></search><sort><creationdate>19821101</creationdate><title>Photochemistry of benzene and oxygen in supersonic cluster beams</title><author>Knee, J. L ; Otis, C. E ; Johnson, Philip M</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a328t-81572ab9958db9496fed3e244c931b52265f6c931201c5fa5b92941a911c3a993</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1982</creationdate><topic>400500 - Photochemistry</topic><topic>AIR TRANSPORT</topic><topic>AROMATICS</topic><topic>BEAMS</topic><topic>BENZENE</topic><topic>CHEMISTRY</topic><topic>CLUSTER BEAMS</topic><topic>ELEMENTS</topic><topic>HYDROCARBONS</topic><topic>INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY</topic><topic>MASS SPECTRA</topic><topic>NONMETALS</topic><topic>ORGANIC COMPOUNDS</topic><topic>OXYGEN</topic><topic>PHOTOCHEMISTRY</topic><topic>SPECTRA</topic><topic>SUPERSONIC TRANSPORT</topic><topic>TRANSPORT</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Knee, J. L</creatorcontrib><creatorcontrib>Otis, C. E</creatorcontrib><creatorcontrib>Johnson, Philip M</creatorcontrib><creatorcontrib>State Univ. of New York, Stony Brook</creatorcontrib><collection>Istex</collection><collection>CrossRef</collection><collection>OSTI.GOV</collection><jtitle>J. Phys. Chem.; (United States)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Knee, J. L</au><au>Otis, C. E</au><au>Johnson, Philip M</au><aucorp>State Univ. of New York, Stony Brook</aucorp><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Photochemistry of benzene and oxygen in supersonic cluster beams</atitle><jtitle>J. Phys. Chem.; (United States)</jtitle><addtitle>J. Phys. Chem</addtitle><date>1982-11-01</date><risdate>1982</risdate><volume>86</volume><issue>23</issue><spage>4467</spage><epage>4469</epage><pages>4467-4469</pages><issn>0022-3654</issn><eissn>1541-5740</eissn><abstract>A reaction is seen to occur between benzene and oxygen in a supersonic beam when mixed clusters are irradiated by 193nm. This reaction has been investigated by multiphoton ionization mass spectrometry, with primary reaction products including the introduction of up to four oxygen atoms onto the benzene, as well as species resulting from hydrogen abstraction. A two laser experiment indicates that the initial step in the photochemical reaction results in a neutral species which lives for longer than 100 ..mu..s.</abstract><cop>United States</cop><pub>American Chemical Society</pub><doi>10.1021/j100220a002</doi><tpages>3</tpages></addata></record> |
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| ispartof | J. Phys. Chem.; (United States), 1982-11, Vol.86 (23), p.4467-4469 |
| issn | 0022-3654 1541-5740 |
| language | eng |
| recordid | cdi_crossref_primary_10_1021_j100220a002 |
| source | ACS Publications |
| subjects | 400500 - Photochemistry AIR TRANSPORT AROMATICS BEAMS BENZENE CHEMISTRY CLUSTER BEAMS ELEMENTS HYDROCARBONS INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY MASS SPECTRA NONMETALS ORGANIC COMPOUNDS OXYGEN PHOTOCHEMISTRY SPECTRA SUPERSONIC TRANSPORT TRANSPORT |
| title | Photochemistry of benzene and oxygen in supersonic cluster beams |
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