Base Hydrolysis of HMX and HMX-Based Plastic-Bonded Explosives with Sodium Hydroxide between 100 and 155 °C

The degradation of HMX-based high explosives (HMX, PBX 9404, and PBX 9501) with sodium hydroxide solutions is described. To obtain practicable reaction rates, the reaction was carried out in a pressurized reactor at temperatures up to about 155 °C. Above about 70 °C, mass transfer rates significantl...

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Veröffentlicht in:	Industrial & engineering chemistry research 1999-06, Vol.38 (6), p.2254-2259
Hauptverfasser:	Bishop, Robert L, Flesner, Raymond L, Dell'Orco, Philip C, Spontarelli, Terry, Larson, Sheldon A, Bell, David A
Format:	Artikel
Sprache:	eng
Schlagworte:	ALKALINE HYDROLYSIS AQUEOUS SOLUTIONS CHEMICAL EXPLOSIVES CHEMICAL REACTION KINETICS DECOMPOSITION EXPERIMENTAL DATA MASS TRANSFER MATHEMATICAL MODELS MILITARY TECHNOLOGY, WEAPONRY, AND NATIONAL DEFENSE SODIUM HYDROXIDES
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