Bis-Triazole-Appended Azobenzene Chromophore for Selective Sensing of Copper(II) Ion
A Cu2+-specific colorimetric sensor of bis-triazole-appended azobenzene receptors I and II was designed and synthesized. Receptor II shows high selectivity toward Cu2+ in acetonitrile/water (80:20, v/v) solution based on the internal charge transfer (ICT) mechanism. The tridentate coordination behav...
Gespeichert in:
| Veröffentlicht in: | Industrial & engineering chemistry research 2011-07, Vol.50 (13), p.8225-8229 |
|---|---|
| Hauptverfasser: | , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 8229 |
|---|---|
| container_issue | 13 |
| container_start_page | 8225 |
| container_title | Industrial & engineering chemistry research |
| container_volume | 50 |
| creator | Hrishikesan, Elango Saravanan, Chinnusamy Kannan, Palaninathan |
| description | A Cu2+-specific colorimetric sensor of bis-triazole-appended azobenzene receptors I and II was designed and synthesized. Receptor II shows high selectivity toward Cu2+ in acetonitrile/water (80:20, v/v) solution based on the internal charge transfer (ICT) mechanism. The tridentate coordination behavior was proposed with 1:1 stoichiometry between receptor II and Cu2+. Herein, the Cu2+ gives rise to a large change in the absorption spectra (from red to pale yellow) that is clearly visible to the naked eye. |
| doi_str_mv | 10.1021/ie200548j |
| format | Article |
| fullrecord | <record><control><sourceid>acs_cross</sourceid><recordid>TN_cdi_crossref_primary_10_1021_ie200548j</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>b447395144</sourcerecordid><originalsourceid>FETCH-LOGICAL-a289t-2dfd341eb0e591a8f9750d223313cbf216e2bba3f0a152d5b67ee8c87090ba213</originalsourceid><addsrcrecordid>eNptkE1LAzEYhIMoWKsH_0Eugj1E89nNHuvix0LBg_W8ZLNvbMo2WZIq2F_vilIvnmYOzwzMIHTJ6A2jnN164JQqqTdHaMIUp0RRqY7RhGqtidJanaKznDd0hJSUE7S685mskjf72ANZDAOEDjq82McWwh4C4Gqd4jYO65gAu5jwC_Rgd_4DRheyD284OlzFMZmu63qG6xjO0YkzfYaLX52i14f7VfVEls-PdbVYEsN1uSO8c52QDFoKqmRGu7JQtONcCCZs6zibA29bIxw145ROtfMCQFtd0JK2hjMxRbOfXptizglcMyS_NemzYbT5vqM53DGyVz_sYLI1vUsmWJ8PAS6F4EwWf5yxudnE9xTGBf_0fQE7BWrz</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>Bis-Triazole-Appended Azobenzene Chromophore for Selective Sensing of Copper(II) Ion</title><source>American Chemical Society Journals</source><creator>Hrishikesan, Elango ; Saravanan, Chinnusamy ; Kannan, Palaninathan</creator><creatorcontrib>Hrishikesan, Elango ; Saravanan, Chinnusamy ; Kannan, Palaninathan</creatorcontrib><description>A Cu2+-specific colorimetric sensor of bis-triazole-appended azobenzene receptors I and II was designed and synthesized. Receptor II shows high selectivity toward Cu2+ in acetonitrile/water (80:20, v/v) solution based on the internal charge transfer (ICT) mechanism. The tridentate coordination behavior was proposed with 1:1 stoichiometry between receptor II and Cu2+. Herein, the Cu2+ gives rise to a large change in the absorption spectra (from red to pale yellow) that is clearly visible to the naked eye.</description><identifier>ISSN: 0888-5885</identifier><identifier>EISSN: 1520-5045</identifier><identifier>DOI: 10.1021/ie200548j</identifier><identifier>CODEN: IECRED</identifier><language>eng</language><publisher>Washington, DC: American Chemical Society</publisher><subject>Applied sciences ; Chemical engineering ; Exact sciences and technology ; Separations</subject><ispartof>Industrial & engineering chemistry research, 2011-07, Vol.50 (13), p.8225-8229</ispartof><rights>Copyright © 2011 American Chemical Society</rights><rights>2015 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-a289t-2dfd341eb0e591a8f9750d223313cbf216e2bba3f0a152d5b67ee8c87090ba213</citedby><cites>FETCH-LOGICAL-a289t-2dfd341eb0e591a8f9750d223313cbf216e2bba3f0a152d5b67ee8c87090ba213</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://pubs.acs.org/doi/pdf/10.1021/ie200548j$$EPDF$$P50$$Gacs$$H</linktopdf><linktohtml>$$Uhttps://pubs.acs.org/doi/10.1021/ie200548j$$EHTML$$P50$$Gacs$$H</linktohtml><link.rule.ids>314,780,784,2765,27076,27924,27925,56738,56788</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=24332147$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Hrishikesan, Elango</creatorcontrib><creatorcontrib>Saravanan, Chinnusamy</creatorcontrib><creatorcontrib>Kannan, Palaninathan</creatorcontrib><title>Bis-Triazole-Appended Azobenzene Chromophore for Selective Sensing of Copper(II) Ion</title><title>Industrial & engineering chemistry research</title><addtitle>Ind. Eng. Chem. Res</addtitle><description>A Cu2+-specific colorimetric sensor of bis-triazole-appended azobenzene receptors I and II was designed and synthesized. Receptor II shows high selectivity toward Cu2+ in acetonitrile/water (80:20, v/v) solution based on the internal charge transfer (ICT) mechanism. The tridentate coordination behavior was proposed with 1:1 stoichiometry between receptor II and Cu2+. Herein, the Cu2+ gives rise to a large change in the absorption spectra (from red to pale yellow) that is clearly visible to the naked eye.</description><subject>Applied sciences</subject><subject>Chemical engineering</subject><subject>Exact sciences and technology</subject><subject>Separations</subject><issn>0888-5885</issn><issn>1520-5045</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2011</creationdate><recordtype>article</recordtype><recordid>eNptkE1LAzEYhIMoWKsH_0Eugj1E89nNHuvix0LBg_W8ZLNvbMo2WZIq2F_vilIvnmYOzwzMIHTJ6A2jnN164JQqqTdHaMIUp0RRqY7RhGqtidJanaKznDd0hJSUE7S685mskjf72ANZDAOEDjq82McWwh4C4Gqd4jYO65gAu5jwC_Rgd_4DRheyD284OlzFMZmu63qG6xjO0YkzfYaLX52i14f7VfVEls-PdbVYEsN1uSO8c52QDFoKqmRGu7JQtONcCCZs6zibA29bIxw145ROtfMCQFtd0JK2hjMxRbOfXptizglcMyS_NemzYbT5vqM53DGyVz_sYLI1vUsmWJ8PAS6F4EwWf5yxudnE9xTGBf_0fQE7BWrz</recordid><startdate>20110706</startdate><enddate>20110706</enddate><creator>Hrishikesan, Elango</creator><creator>Saravanan, Chinnusamy</creator><creator>Kannan, Palaninathan</creator><general>American Chemical Society</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20110706</creationdate><title>Bis-Triazole-Appended Azobenzene Chromophore for Selective Sensing of Copper(II) Ion</title><author>Hrishikesan, Elango ; Saravanan, Chinnusamy ; Kannan, Palaninathan</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a289t-2dfd341eb0e591a8f9750d223313cbf216e2bba3f0a152d5b67ee8c87090ba213</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2011</creationdate><topic>Applied sciences</topic><topic>Chemical engineering</topic><topic>Exact sciences and technology</topic><topic>Separations</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Hrishikesan, Elango</creatorcontrib><creatorcontrib>Saravanan, Chinnusamy</creatorcontrib><creatorcontrib>Kannan, Palaninathan</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><jtitle>Industrial & engineering chemistry research</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Hrishikesan, Elango</au><au>Saravanan, Chinnusamy</au><au>Kannan, Palaninathan</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Bis-Triazole-Appended Azobenzene Chromophore for Selective Sensing of Copper(II) Ion</atitle><jtitle>Industrial & engineering chemistry research</jtitle><addtitle>Ind. Eng. Chem. Res</addtitle><date>2011-07-06</date><risdate>2011</risdate><volume>50</volume><issue>13</issue><spage>8225</spage><epage>8229</epage><pages>8225-8229</pages><issn>0888-5885</issn><eissn>1520-5045</eissn><coden>IECRED</coden><abstract>A Cu2+-specific colorimetric sensor of bis-triazole-appended azobenzene receptors I and II was designed and synthesized. Receptor II shows high selectivity toward Cu2+ in acetonitrile/water (80:20, v/v) solution based on the internal charge transfer (ICT) mechanism. The tridentate coordination behavior was proposed with 1:1 stoichiometry between receptor II and Cu2+. Herein, the Cu2+ gives rise to a large change in the absorption spectra (from red to pale yellow) that is clearly visible to the naked eye.</abstract><cop>Washington, DC</cop><pub>American Chemical Society</pub><doi>10.1021/ie200548j</doi><tpages>5</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0888-5885 |
| ispartof | Industrial & engineering chemistry research, 2011-07, Vol.50 (13), p.8225-8229 |
| issn | 0888-5885 1520-5045 |
| language | eng |
| recordid | cdi_crossref_primary_10_1021_ie200548j |
| source | American Chemical Society Journals |
| subjects | Applied sciences Chemical engineering Exact sciences and technology Separations |
| title | Bis-Triazole-Appended Azobenzene Chromophore for Selective Sensing of Copper(II) Ion |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2024-12-22T10%3A35%3A28IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-acs_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Bis-Triazole-Appended%20Azobenzene%20Chromophore%20for%20Selective%20Sensing%20of%20Copper(II)%20Ion&rft.jtitle=Industrial%20&%20engineering%20chemistry%20research&rft.au=Hrishikesan,%20Elango&rft.date=2011-07-06&rft.volume=50&rft.issue=13&rft.spage=8225&rft.epage=8229&rft.pages=8225-8229&rft.issn=0888-5885&rft.eissn=1520-5045&rft.coden=IECRED&rft_id=info:doi/10.1021/ie200548j&rft_dat=%3Cacs_cross%3Eb447395144%3C/acs_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_id=info:pmid/&rfr_iscdi=true |