Nucleophilic Reactions at Cationic Centers in Ionic Liquids and Molecular Solvents

We report a quantitative comparison of the rates of nucleophilic reactions in ionic liquids and molecular solvents taking place at a cationic center. Cationic sulfonium electrophiles were reacted with three amine nucleophiles (n-butylamine, di-n-butylamine, and tri-n-butylamine) in several molecular...

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Veröffentlicht in:Industrial & engineering chemistry research 2008-02, Vol.47 (3), p.638-644
Hauptverfasser: Ranieri, Giuseppe, Hallett, Jason P, Welton, Tom
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Sprache:eng
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