Effect of carbon dioxide on the kinetics of the Fischer-Tropsch synthesis on iron catalysts
A recently proposed kinetic expression applicable to feed ratios H/sub 2//CO of 0.8 or less correlates the synthesis rate by an equation containing an inhibition term for CO/sub 2/ and assumes that water vapor concentrations are too low to offer significant inhibition. Experimental studies here with...
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| Veröffentlicht in: | Ind. Eng. Chem. Res.; (United States) 1989-01, Vol.28 (1), p.9-12 |
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| container_title | Ind. Eng. Chem. Res.; (United States) |
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| creator | Yates, Ian C Satterfield, Charles N |
| description | A recently proposed kinetic expression applicable to feed ratios H/sub 2//CO of 0.8 or less correlates the synthesis rate by an equation containing an inhibition term for CO/sub 2/ and assumes that water vapor concentrations are too low to offer significant inhibition. Experimental studies here with synthesis gas of H/sub 2//CO ratios of 0.67-0.72 to which CO/sub 2/ was added show, in contrast, that CO/sub 2/ is relatively inert. The data are well correlated by an equation developed by Huff that contains an inhibition term for H/sub 2/O but not for CO/sub 2/. The authors suggest that the inhibition attributed to CO/sub 2/ was instead actually caused by H/sub 2/O formed by the reverse water gas shift reaction. |
| doi_str_mv | 10.1021/ie00085a003 |
| format | Article |
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Experimental studies here with synthesis gas of H/sub 2//CO ratios of 0.67-0.72 to which CO/sub 2/ was added show, in contrast, that CO/sub 2/ is relatively inert. The data are well correlated by an equation developed by Huff that contains an inhibition term for H/sub 2/O but not for CO/sub 2/. The authors suggest that the inhibition attributed to CO/sub 2/ was instead actually caused by H/sub 2/O formed by the reverse water gas shift reaction.</description><identifier>ISSN: 0888-5885</identifier><identifier>EISSN: 1520-5045</identifier><identifier>DOI: 10.1021/ie00085a003</identifier><identifier>CODEN: IECRED</identifier><language>eng</language><publisher>Washington, DC: American Chemical Society</publisher><subject>01 COAL, LIGNITE, AND PEAT ; 010408 - Coal, Lignite, & Peat- C1 Processes- (1987-) ; 08 HYDROGEN ; 080108 - Hydrogen- Production- Steam-Iron Process ; CARBON COMPOUNDS ; CARBON DIOXIDE ; CARBON MONOXIDE ; CARBON OXIDES ; CATALYSTS ; CHALCOGENIDES ; CHEMICAL REACTION KINETICS ; CHEMICAL REACTIONS ; Chemistry ; DATA ; ELEMENTS ; Exact sciences and technology ; EXPERIMENTAL DATA ; FISCHER-TROPSCH SYNTHESIS ; FLUID INJECTION ; FLUIDS ; GAS INJECTION ; GASES ; HYDROGEN ; INFORMATION ; IRON ; KINETICS ; Kinetics and mechanisms ; METALS ; NONMETALS ; NUMERICAL DATA ; Organic chemistry ; OXIDES ; OXYGEN COMPOUNDS ; REACTION KINETICS ; Reactivity and mechanisms ; SYNTHESIS GAS ; TRANSITION ELEMENTS ; VAPORS ; WATER VAPOR</subject><ispartof>Ind. 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Res.; (United States), 1989-01, Vol.28 (1), p.9-12</ispartof><rights>1990 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-a393t-31596bf4c3ea61f2e4f65cfbad13fb9c68fc938f00604396e7e84794222166233</citedby></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://pubs.acs.org/doi/pdf/10.1021/ie00085a003$$EPDF$$P50$$Gacs$$H</linktopdf><linktohtml>$$Uhttps://pubs.acs.org/doi/10.1021/ie00085a003$$EHTML$$P50$$Gacs$$H</linktohtml><link.rule.ids>314,780,784,885,2765,27076,27924,27925,56738,56788</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=6773656$$DView record in Pascal Francis$$Hfree_for_read</backlink><backlink>$$Uhttps://www.osti.gov/biblio/6022630$$D View this record in Osti.gov$$Hfree_for_read</backlink></links><search><creatorcontrib>Yates, Ian C</creatorcontrib><creatorcontrib>Satterfield, Charles N</creatorcontrib><creatorcontrib>Dept. of Chemical Engineering, MIT, Cambridge, MA (US)</creatorcontrib><title>Effect of carbon dioxide on the kinetics of the Fischer-Tropsch synthesis on iron catalysts</title><title>Ind. Eng. Chem. Res.; (United States)</title><addtitle>Ind. Eng. Chem. Res</addtitle><description>A recently proposed kinetic expression applicable to feed ratios H/sub 2//CO of 0.8 or less correlates the synthesis rate by an equation containing an inhibition term for CO/sub 2/ and assumes that water vapor concentrations are too low to offer significant inhibition. Experimental studies here with synthesis gas of H/sub 2//CO ratios of 0.67-0.72 to which CO/sub 2/ was added show, in contrast, that CO/sub 2/ is relatively inert. The data are well correlated by an equation developed by Huff that contains an inhibition term for H/sub 2/O but not for CO/sub 2/. The authors suggest that the inhibition attributed to CO/sub 2/ was instead actually caused by H/sub 2/O formed by the reverse water gas shift reaction.</description><subject>01 COAL, LIGNITE, AND PEAT</subject><subject>010408 - Coal, Lignite, & Peat- C1 Processes- (1987-)</subject><subject>08 HYDROGEN</subject><subject>080108 - Hydrogen- Production- Steam-Iron Process</subject><subject>CARBON COMPOUNDS</subject><subject>CARBON DIOXIDE</subject><subject>CARBON MONOXIDE</subject><subject>CARBON OXIDES</subject><subject>CATALYSTS</subject><subject>CHALCOGENIDES</subject><subject>CHEMICAL REACTION KINETICS</subject><subject>CHEMICAL REACTIONS</subject><subject>Chemistry</subject><subject>DATA</subject><subject>ELEMENTS</subject><subject>Exact sciences and technology</subject><subject>EXPERIMENTAL DATA</subject><subject>FISCHER-TROPSCH SYNTHESIS</subject><subject>FLUID INJECTION</subject><subject>FLUIDS</subject><subject>GAS INJECTION</subject><subject>GASES</subject><subject>HYDROGEN</subject><subject>INFORMATION</subject><subject>IRON</subject><subject>KINETICS</subject><subject>Kinetics and mechanisms</subject><subject>METALS</subject><subject>NONMETALS</subject><subject>NUMERICAL DATA</subject><subject>Organic chemistry</subject><subject>OXIDES</subject><subject>OXYGEN COMPOUNDS</subject><subject>REACTION KINETICS</subject><subject>Reactivity and mechanisms</subject><subject>SYNTHESIS GAS</subject><subject>TRANSITION ELEMENTS</subject><subject>VAPORS</subject><subject>WATER VAPOR</subject><issn>0888-5885</issn><issn>1520-5045</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1989</creationdate><recordtype>article</recordtype><recordid>eNpt0MtKAzEUBuAgCtbqyhcYRHAho7lPZqml9VZQsG50EdI0oWnrTMmJ0L69KSPiwk1yknwnJD9CpwRfEUzJdXAYYyUMxmwP9YiguBSYi33Uw0qpUiglDtERwCIzITjvoY-h986movWFNXHaNsUstJswc0Uu09wVy9C4FCzsxG49CmDnLpaT2K5zVcC2ydsQYNcQYh6sSWa1hQTH6MCbFbiTn7mP3kbDyeC-HD_fPQxuxqVhNUslI6KWU88tc0YSTx33Ulg_NTPC_LS2UnlbM-UxlpizWrrKKV7VnFJKpKSM9dFZd28LKWiwITk7t23T5I9piSmVDGd02SEbW4DovF7H8GniVhOsd-HpP-Flfd7ptQFrVj6axgb4bZFVxaSQmZUdC5Dc5vfYxGUmrBJ68vKq-Zg-PbL3St9mf9F5Y0Ev2q_Y5Fz-fcA3b-6JOA</recordid><startdate>19890101</startdate><enddate>19890101</enddate><creator>Yates, Ian C</creator><creator>Satterfield, Charles N</creator><general>American Chemical Society</general><scope>BSCLL</scope><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>OTOTI</scope></search><sort><creationdate>19890101</creationdate><title>Effect of carbon dioxide on the kinetics of the Fischer-Tropsch synthesis on iron catalysts</title><author>Yates, Ian C ; Satterfield, Charles N</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a393t-31596bf4c3ea61f2e4f65cfbad13fb9c68fc938f00604396e7e84794222166233</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1989</creationdate><topic>01 COAL, LIGNITE, AND PEAT</topic><topic>010408 - Coal, Lignite, & Peat- C1 Processes- (1987-)</topic><topic>08 HYDROGEN</topic><topic>080108 - Hydrogen- Production- Steam-Iron Process</topic><topic>CARBON COMPOUNDS</topic><topic>CARBON DIOXIDE</topic><topic>CARBON MONOXIDE</topic><topic>CARBON OXIDES</topic><topic>CATALYSTS</topic><topic>CHALCOGENIDES</topic><topic>CHEMICAL REACTION KINETICS</topic><topic>CHEMICAL REACTIONS</topic><topic>Chemistry</topic><topic>DATA</topic><topic>ELEMENTS</topic><topic>Exact sciences and technology</topic><topic>EXPERIMENTAL DATA</topic><topic>FISCHER-TROPSCH SYNTHESIS</topic><topic>FLUID INJECTION</topic><topic>FLUIDS</topic><topic>GAS INJECTION</topic><topic>GASES</topic><topic>HYDROGEN</topic><topic>INFORMATION</topic><topic>IRON</topic><topic>KINETICS</topic><topic>Kinetics and mechanisms</topic><topic>METALS</topic><topic>NONMETALS</topic><topic>NUMERICAL DATA</topic><topic>Organic chemistry</topic><topic>OXIDES</topic><topic>OXYGEN COMPOUNDS</topic><topic>REACTION KINETICS</topic><topic>Reactivity and mechanisms</topic><topic>SYNTHESIS GAS</topic><topic>TRANSITION ELEMENTS</topic><topic>VAPORS</topic><topic>WATER VAPOR</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Yates, Ian C</creatorcontrib><creatorcontrib>Satterfield, Charles N</creatorcontrib><creatorcontrib>Dept. of Chemical Engineering, MIT, Cambridge, MA (US)</creatorcontrib><collection>Istex</collection><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>OSTI.GOV</collection><jtitle>Ind. Eng. Chem. Res.; (United States)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Yates, Ian C</au><au>Satterfield, Charles N</au><aucorp>Dept. of Chemical Engineering, MIT, Cambridge, MA (US)</aucorp><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Effect of carbon dioxide on the kinetics of the Fischer-Tropsch synthesis on iron catalysts</atitle><jtitle>Ind. Eng. Chem. Res.; (United States)</jtitle><addtitle>Ind. Eng. Chem. Res</addtitle><date>1989-01-01</date><risdate>1989</risdate><volume>28</volume><issue>1</issue><spage>9</spage><epage>12</epage><pages>9-12</pages><issn>0888-5885</issn><eissn>1520-5045</eissn><coden>IECRED</coden><abstract>A recently proposed kinetic expression applicable to feed ratios H/sub 2//CO of 0.8 or less correlates the synthesis rate by an equation containing an inhibition term for CO/sub 2/ and assumes that water vapor concentrations are too low to offer significant inhibition. Experimental studies here with synthesis gas of H/sub 2//CO ratios of 0.67-0.72 to which CO/sub 2/ was added show, in contrast, that CO/sub 2/ is relatively inert. The data are well correlated by an equation developed by Huff that contains an inhibition term for H/sub 2/O but not for CO/sub 2/. The authors suggest that the inhibition attributed to CO/sub 2/ was instead actually caused by H/sub 2/O formed by the reverse water gas shift reaction.</abstract><cop>Washington, DC</cop><pub>American Chemical Society</pub><doi>10.1021/ie00085a003</doi><tpages>4</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0888-5885 |
| ispartof | Ind. Eng. Chem. Res.; (United States), 1989-01, Vol.28 (1), p.9-12 |
| issn | 0888-5885 1520-5045 |
| language | eng |
| recordid | cdi_crossref_primary_10_1021_ie00085a003 |
| source | ACS Publications |
| subjects | 01 COAL, LIGNITE, AND PEAT 010408 - Coal, Lignite, & Peat- C1 Processes- (1987-) 08 HYDROGEN 080108 - Hydrogen- Production- Steam-Iron Process CARBON COMPOUNDS CARBON DIOXIDE CARBON MONOXIDE CARBON OXIDES CATALYSTS CHALCOGENIDES CHEMICAL REACTION KINETICS CHEMICAL REACTIONS Chemistry DATA ELEMENTS Exact sciences and technology EXPERIMENTAL DATA FISCHER-TROPSCH SYNTHESIS FLUID INJECTION FLUIDS GAS INJECTION GASES HYDROGEN INFORMATION IRON KINETICS Kinetics and mechanisms METALS NONMETALS NUMERICAL DATA Organic chemistry OXIDES OXYGEN COMPOUNDS REACTION KINETICS Reactivity and mechanisms SYNTHESIS GAS TRANSITION ELEMENTS VAPORS WATER VAPOR |
| title | Effect of carbon dioxide on the kinetics of the Fischer-Tropsch synthesis on iron catalysts |
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