Oxidation of Simple Alcohols in Supercritical Water III. Formation of Intermediates from Ethanol

Raman spectroscopy is used as an in situ diagnostic to measure the oxidation of ethanol by oxygen in supercritical water. An elementary reaction mechanism based on the work of Marinov is shown to predict accurately many of the experimental observations. Experimental measurements are reported at 24.5...

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Veröffentlicht in:	Industrial & engineering chemistry research 2001-01, Vol.40 (1), p.86-93
Hauptverfasser:	Rice, Steven F, Croiset, Eric
Format:	Artikel
Sprache:	eng
Schlagworte:	Chemistry Exact sciences and technology Kinetics and mechanisms Organic chemistry Reactivity and mechanisms
Online-Zugang:	Volltext
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