Vanadium Complexes of the N(CH2CH2S)3 3- and O(CH2CH2S)2 2- Ligands with Coligands Relevant to Nitrogen Fixation Processes

Vanadium(III) and vanadium(V) complexes derived from the tris(2-thiolatoethyl)amine ligand [(NS 3)3-] and the bis(2-thiolatoethyl)ether ligand [(OS 2)2-] have been synthesized with the aim of investigating the potential of these vanadium sites to bind dinitrogen and activate its reduction. Evidence...

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Veröffentlicht in:Inorganic chemistry 2000-08, Vol.39 (16), p.3485-3498
Hauptverfasser: Davies, Sian C, Hughes, David L, Janas, Zofia, Jerzykiewicz, Lucjan B, Richards, Raymond L, Sanders, J. Roger, Silverston, James E, Sobota, Piotr
Format: Artikel
Sprache:eng
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