On the Second-Order Nonlinear Optical Structure−Property Relationships of Metal Chromophores

On the Second-Order Nonlinear Optical Structure−Property Relationships of Metal Chromophores

The synthesis and solvent-dependent second-order polarizability, β, responses of three new platinum(II) chromophores are reported. A strong correlation between the metal chromophore electronic structure and the second-order polarizability is observed that substantiates the use of the two-state model...

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Veröffentlicht in:Inorganic chemistry 1999-01, Vol.38 (2), p.287-289
Hauptverfasser: Base, Karel, Tierney, Mark T, Fort, Alain, Muller, Jacques, Grinstaff, Mark W
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container_title Inorganic chemistry
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creator Base, Karel
Tierney, Mark T
Fort, Alain
Muller, Jacques
Grinstaff, Mark W
description The synthesis and solvent-dependent second-order polarizability, β, responses of three new platinum(II) chromophores are reported. A strong correlation between the metal chromophore electronic structure and the second-order polarizability is observed that substantiates the use of the two-state model to design, optimize, and study new NLO chromophores.
doi_str_mv 10.1021/ic980872q
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title On the Second-Order Nonlinear Optical Structure−Property Relationships of Metal Chromophores
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