$Combined X-ray Diffraction and Density Functional Study of [Ni(NO)(η5-Cp)] in the Ground and Light-Induced Metastable States$

Combined X-ray Diffraction and Density Functional Study of [Ni(NO)(η5-Cp)] in the Ground and Light-Induced Metastable States

The crystal structure of [Ni(NO)(η5-Cp*)] in the light-induced metastable state was determined by X-ray diffraction at 25 K of a crystal with a 47% metastable-state population. The most significant geometrical change is the formation of a side (η2) bound structure with an Ni−N−O angle of 92(1)°, com...

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Veröffentlicht in:	Inorganic chemistry 1998-04, Vol.37 (7), p.1519-1526
Hauptverfasser:	Fomitchev, Dmitry V, Furlani, Thomas R, Coppens, Philip
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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