Synthesis, Electrochemistry, and Imido Transfer Reactions of (TTP)Ti(η2-PhNNPh)

Synthesis, Electrochemistry, and Imido Transfer Reactions of (TTP)Ti(η2-PhNNPh)

Treatment of (TTP)Ti(η2-RC⋮CR) (R = Et or Ph) with PhNNPh results in formation of the azobenzene adduct (TTP)Ti(η2-PhNNPh) (1) in good isolated yield. Complex 1 reacts with (TTP)Ti(η2-RC⋮CR) at elevated temperatures to cleanly afford 2 equiv of the phenylimido compound, (TTP)TiNPh (2). The azoben...

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Veröffentlicht in:Inorganic chemistry 1998-01, Vol.37 (1), p.1-4
Hauptverfasser: Gray, Steven D, Thorman, Joseph L, Adamian, Victor A, Kadish, Karl M, Woo, L. Keith
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container_title Inorganic chemistry
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creator Gray, Steven D
Thorman, Joseph L
Adamian, Victor A
Kadish, Karl M
Woo, L. Keith
description Treatment of (TTP)Ti(η2-RC⋮CR) (R = Et or Ph) with PhNNPh results in formation of the azobenzene adduct (TTP)Ti(η2-PhNNPh) (1) in good isolated yield. Complex 1 reacts with (TTP)Ti(η2-RC⋮CR) at elevated temperatures to cleanly afford 2 equiv of the phenylimido compound, (TTP)TiNPh (2). The azobenzene complex, 1, is also formed in low yields by the reaction of the (TTP)TiNPh (2) with excess 1,2-diphenylhydrazine. The electrochemistry of the azobenzene adduct (1) and the phenylimido complex (2) is investigated by cyclic voltammetry experiments.
doi_str_mv 10.1021/ic970952e
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title Synthesis, Electrochemistry, and Imido Transfer Reactions of (TTP)Ti(η2-PhNNPh)
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