Surface Complexation Description of the Dissolution of Chromium(III) Hydrous Oxides by Oxalic Acid

Aqueous oxalic acid forms surface CrIII−oxalato complexes with suspended chromium(III) oxide particles; the FTIR spectra demonstrate that both carboxylate groups of the ligand are bound to surface CrIII. Surface complexation is followed by changes in the surface redox potential toward more negative...

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Veröffentlicht in:Inorganic chemistry 1997-12, Vol.36 (27), p.6423-6430
Hauptverfasser: García Rodenas, Luis A, Iglesias, Alberto M, Weisz, Ariel D, Morando, Pedro J, Blesa, Miguel A
Format: Artikel
Sprache:eng
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