Complexes Containing 2,9-Bis(p-biphenylyl)-1,10-phenanthroline Units Incorporated into a 56-Membered Ring. Synthesis, Electrochemistry, and Photophysical Properties

We synthesized a new macrocycle (1) which is made of a 56-membered ring and contains two 2,9-bis(p-biphenylyl)-1,10-phenanthroline ligands. Then we prepared the complexes [Cu(1)(2)]+ (a catenate species), [Cu(3)2]+, [Cu(2)(3)]+ (a threaded species), Re(1)(CO)3Cl, and Re(3)(CO)3Cl, where 2 is a 33-me...

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Veröffentlicht in:Inorganic chemistry 1997-11, Vol.36 (23), p.5329-5338
Hauptverfasser: Kern, Jean-Marc, Sauvage, Jean-Pierre, Weidmann, Jean-Luc, Armaroli, Nicola, Flamigni, Lucia, Ceroni, Paola, Balzani, Vincenzo
Format: Artikel
Sprache:eng
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