Syntheses and Structures of [Sn{NR}2{Sn(μ-NMe2)}2]:  Model Intermediates in the Formation of Imido Group 14 Cages and Rings [R = 2,6-Pr i 2C6H3 (Dipp), 2,4,6-Me3C6H2 (Mes)]

The 1:1 reactions of aliphatic primary amines [RNH2] with [Sn(NMe2)2] yield the imido Sn(II) cubanes [SnNR]4; however, for highly sterically crowded amines this reaction is retarded and the model intermediates [Sn{NR}2{Sn(μ-NMe2)}2] [R = 2,6-Pr i C6H3 (Dipp) (1), 2,4,6-Me3C6H2 (Mes) (2)] can be isol...

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Veröffentlicht in:	Inorganic chemistry 1997-11, Vol.36 (23), p.5202-5205
Hauptverfasser:	Allan, Robert E, Beswick, Michael A, Coggan, Georgina R, Raithby, Paul R, Wheatley, Andrew E. H, Wright, Dominic S
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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