A New Bridging Ligand for the [Mo2]4+ Dimer:  Syntheses and X-ray Crystal Structures of the Redox Pair [Mo2{μ-η2-(NPh)2CNHPh}4]0

The quadruply bonded molybdenum dimer [Mo2{μ-η2-(NPh)2CNHPh}4] (1), bridged by four triphenylguanidine anion (guanidino) ligands, has been synthesized and structurally characterized. The guanidino ligands greatly stabilize the oxidized forms of this complex, and it is reversibly oxidized to the red...

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Veröffentlicht in:	Inorganic chemistry 1997-02, Vol.36 (5), p.867-871
Hauptverfasser:	Bailey, Philip J, Bone, Simon F, Mitchell, Lindsey A, Parsons, Simon, Taylor, Kenneth J, Yellowlees, Lesley J
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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