Synthesis and Structures of Intramolecularly Base-Coordinated Aryl Group 15 Compounds

Several group 15 compounds of the type EAr3 (Ar = 2-[(dimethylamino)methyl]phenyl; E = As (4), Sb (5), Bi (6)) have been prepared via salt elimination reactions of 2-(Me2NCH2)C6H4Li and ECl3. Treatment of the lithium salt of the 8-(dimethylamino)-1-naphthyl ligand (Ar‘) with AsCl3 afforded a triaryl...

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Veröffentlicht in:Inorganic chemistry 1996-10, Vol.35 (21), p.6179-6183
Hauptverfasser: Kamepalli, Smuruthi, Carmalt, Claire J, Culp, Robert D, Cowley, Alan H, Jones, Richard A, Norman, Nicholas C
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Sprache:eng
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