Synthesis and Structural Characterization of Compounds Containing the [Zr6Cl18H5]3- Cluster Anion. Determination of the Number of Cluster Hydrogen Atoms

Reduction of ZrCl4 with HSnBu3 followed by addition of [R4A]Cl resulted in the formation of [R4A]3[Zr6Cl18H5] (2a, R = Ph, A = P; 2b, R = n-Pr, A = N; 2c, R = Et, A = N). Six zirconium atoms are arranged as an octahedron with one Cl atom terminally coordinated to each Zr atom and the other 12 Cl ato...

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Veröffentlicht in:	Inorganic chemistry 1997-08, Vol.36 (18), p.4047-4054
Hauptverfasser:	Chen, Linfeng, Cotton, F. Albert, Wojtczak, William A
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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