Photoinduced Electron Transfer and Intramolecular Folding in a Tricarbonylrhenium (Bi)pyridine Based Donor/Crown/Acceptor Assembly:  Dependence on Solvent

The title assembly diplays an emissive rhenium-to-pyridine charge-transfer state that is partially quenched by electron transfer to an attached acceptor (nitrobenzene). Quenching is preceded by intramolecular folding (J. Am. Chem. Soc. 1993, 115, 2048). Variable-temperature quenching measurements ca...

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Veröffentlicht in:Inorganic chemistry 1996-03, Vol.35 (7), p.2032-2035
Hauptverfasser: Berg-Brennan, Christine A, Yoon, Dong I, Slone, Robert V, Kazala, Amy P, Hupp, Joseph T
Format: Artikel
Sprache:eng
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