Synthesis and Electronic Spectra of Fluorinated Aryloxide and Alkoxide [NiX4]2− Anions
Five new homoleptic [NiX4]2− compounds have been prepared with the fluorinated ligands OC6F5 (OArF), OC6H3(CF3)2 (OAr′), and OC4F9 (ORF) and characterized with X-ray crystallography, magnetic susceptibility, and elemental analysis. Electronic spectral studies show that these ligands engender a ligan...
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| Veröffentlicht in: | Inorganic chemistry 2009-05, Vol.48 (10), p.4274-4276 |
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| container_issue | 10 |
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| container_title | Inorganic chemistry |
| container_volume | 48 |
| creator | Zheng, BingNa Miranda, Maria O DiPasquale, Antonio G Golen, James A Rheingold, Arnold L Doerrer, Linda H |
| description | Five new homoleptic [NiX4]2− compounds have been prepared with the fluorinated ligands OC6F5 (OArF), OC6H3(CF3)2 (OAr′), and OC4F9 (ORF) and characterized with X-ray crystallography, magnetic susceptibility, and elemental analysis. Electronic spectral studies show that these ligands engender a ligand-field environment similar to that of fluoride and thus act electronically like fluoride, but with none of the drawbacks of F− as a transition-metal ligand. |
| doi_str_mv | 10.1021/ic9003593 |
| format | Article |
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| ispartof | Inorganic chemistry, 2009-05, Vol.48 (10), p.4274-4276 |
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| title | Synthesis and Electronic Spectra of Fluorinated Aryloxide and Alkoxide [NiX4]2− Anions |
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