Correlation of core electron binding energies with charge distributions for compounds of carbon, silicon, and germanium
Core electron binding energies for analogous compounds of carbon, silicon, and germanium have been measured by X-ray photoelectron spectroscopy in the gas phase. The chemical shifts have been correlated by the electrostatic potential equation using charge distributions from extended Huckel theory, C...
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| Veröffentlicht in: | Inorg. Chem.; (United States) 1974-05, Vol.13 (5), p.1211-1217 |
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| container_end_page | 1217 |
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| container_title | Inorg. Chem.; (United States) |
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| creator | Perry, Winfield B Jolly, William L |
| description | Core electron binding energies for analogous compounds of carbon, silicon, and germanium have been measured by X-ray photoelectron spectroscopy in the gas phase. The chemical shifts have been correlated by the electrostatic potential equation using charge distributions from extended Huckel theory, CNDO/2, and an electronegativity equalization method. The data can be rationalized without any consideration p..pi -->..d..pi.. or p(pi)..-->..d(pi) in the silicon and germanium compounds. |
| doi_str_mv | 10.1021/ic50135a038 |
| format | Article |
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The chemical shifts have been correlated by the electrostatic potential equation using charge distributions from extended Huckel theory, CNDO/2, and an electronegativity equalization method. The data can be rationalized without any consideration p..pi -->..d..pi.. or p(pi)..-->..d(pi) in the silicon and germanium compounds.</description><identifier>ISSN: 0020-1669</identifier><identifier>EISSN: 1520-510X</identifier><identifier>DOI: 10.1021/ic50135a038</identifier><language>eng</language><publisher>United States: American Chemical Society</publisher><subject>400201 - Chemical & Physicochemical Properties ; BINDING ENERGY ; CALCULATION METHODS ; CARBON COMPOUNDS ; CHARGE DISTRIBUTION ; CHEMICAL SHIFT ; CORRELATIONS ; DATA ; DATA FORMS ; ELECTRON SPECTROSCOPY ; ELECTRONIC STRUCTURE ; ENERGY ; EXPERIMENTAL DATA ; FLUIDS ; GASES ; GERMANIUM COMPOUNDS ; INFORMATION ; INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY ; ISOLATED VALUES ; NUMERICAL DATA ; PHOTOELECTRON SPECTROSCOPY ; SILICON COMPOUNDS ; SPECTROSCOPY</subject><ispartof>Inorg. 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Chem.; (United States)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Perry, Winfield B</au><au>Jolly, William L</au><aucorp>Univ. of California, Berkeley</aucorp><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Correlation of core electron binding energies with charge distributions for compounds of carbon, silicon, and germanium</atitle><jtitle>Inorg. Chem.; (United States)</jtitle><addtitle>Inorg. Chem</addtitle><date>1974-05-01</date><risdate>1974</risdate><volume>13</volume><issue>5</issue><spage>1211</spage><epage>1217</epage><pages>1211-1217</pages><issn>0020-1669</issn><eissn>1520-510X</eissn><abstract>Core electron binding energies for analogous compounds of carbon, silicon, and germanium have been measured by X-ray photoelectron spectroscopy in the gas phase. The chemical shifts have been correlated by the electrostatic potential equation using charge distributions from extended Huckel theory, CNDO/2, and an electronegativity equalization method. The data can be rationalized without any consideration p..pi -->..d..pi.. or p(pi)..-->..d(pi) in the silicon and germanium compounds.</abstract><cop>United States</cop><pub>American Chemical Society</pub><doi>10.1021/ic50135a038</doi><tpages>7</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0020-1669 |
| ispartof | Inorg. Chem.; (United States), 1974-05, Vol.13 (5), p.1211-1217 |
| issn | 0020-1669 1520-510X |
| language | eng |
| recordid | cdi_crossref_primary_10_1021_ic50135a038 |
| source | American Chemical Society Journals |
| subjects | 400201 - Chemical & Physicochemical Properties BINDING ENERGY CALCULATION METHODS CARBON COMPOUNDS CHARGE DISTRIBUTION CHEMICAL SHIFT CORRELATIONS DATA DATA FORMS ELECTRON SPECTROSCOPY ELECTRONIC STRUCTURE ENERGY EXPERIMENTAL DATA FLUIDS GASES GERMANIUM COMPOUNDS INFORMATION INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY ISOLATED VALUES NUMERICAL DATA PHOTOELECTRON SPECTROSCOPY SILICON COMPOUNDS SPECTROSCOPY |
| title | Correlation of core electron binding energies with charge distributions for compounds of carbon, silicon, and germanium |
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