Correlation of the Electronic and Geometric Structures in Mononuclear Copper(II) Superoxide Complexes

The geometry of mononuclear copper(II) superoxide complexes has been shown to determine their ground state where side-on bonding leads to a singlet ground state and end-on complexes have triplet ground states. In an apparent contrast to this trend, the recently synthesized (HIPT3tren)CuIIO2 •– (1) w...

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Veröffentlicht in:	Inorganic chemistry 2013-11, Vol.52 (22), p.12872-12874
Hauptverfasser:	Ginsbach, Jake W, Peterson, Ryan L, Cowley, Ryan E, Karlin, Kenneth D, Solomon, Edward I
Format:	Artikel
Sprache:	eng
Schlagworte:	Coordination Complexes - chemistry Copper - chemistry Electrons Magnetic Resonance Spectroscopy Molecular Conformation Superoxides - chemistry
Online-Zugang:	Volltext
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