Effect of N 4‑Substituent Choice on Spin Crossover in Dinuclear Iron(II) Complexes of Bis-Terdentate 1,2,4-Triazole-Based Ligands

Seven new dinuclear iron­(II) complexes of the general formula [FeII 2(PMRT)2]­(BF4)4·solvent, where PMRT is a 4-substituted-3,5-bis­{[(2-pyridylmethyl)-amino]­methyl}-4H-1,2,4-triazole, have been prepared in order to investigate the substituent effect on the spin crossover event. Variable temperatu...

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Veröffentlicht in:	Inorganic chemistry 2013-10, Vol.52 (19), p.11185-11199
Hauptverfasser:	Kitchen, Jonathan A, Olguín, Juan, Kulmaczewski, Rafal, White, Nicholas G, Milway, Victoria A, Jameson, Guy N. L, Tallon, Jeffery L, Brooker, Sally
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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