Aqueous Reductive Dechlorination of Chlorinated Ethylenes with Tetrakis(4-carboxyphenyl)porphyrin Cobalt

The catalytic dechlorination of chlorinated ethylenes by 5,10,15,20-tetrakis(4-carboxyphenyl)porphyrin cobalt ((TCPP)Co), a cobalt complex structurally similar to vitamin B12, was studied. It was found to have superior aqueous-phase dechlorination activity on chlorinated ethylenes (CEs) relative to...

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Veröffentlicht in:	Inorganic chemistry 2005-06, Vol.44 (13), p.4852-4861
Hauptverfasser:	Fritsch, Joseph M, McNeill, Kristopher
Format:	Artikel
Sprache:	eng
Schlagworte:	Catalysis Chlorine - chemistry Crystallography, X-Ray Electrochemistry Ethylenes - chemistry Hydrocarbons, Chlorinated - chemistry Hydrogen-Ion Concentration Kinetics Metalloporphyrins - chemical synthesis Metalloporphyrins - pharmacology Oxidation-Reduction Reducing Agents - chemistry Spectrophotometry, Ultraviolet Time Factors Vitamin B 12 - chemistry Water Pollutants - isolation & purification
Online-Zugang:	Volltext
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