Aqua Ions. 2. Structural Manifestations of the Jahn−Teller Effect in the β-Alums

Variable-temperature single-crystal neutron diffraction structures of the alums CsMIII(SO4)2·12D2O, where MIII = Ti, V, Mn, and Ga, are reported. Structural differences are highlighted by the titanium and manganese alums, which undergo cubic (Pa3̄) to orthorhombic (Pbca) phase transitions at ∼13 and...

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Veröffentlicht in:	Inorganic chemistry 2003-02, Vol.42 (4), p.1350-1365
Hauptverfasser:	Tregenna-Piggott, Philip L. W, Andres, Hans-Peter, McIntyre, Garry J, Best, Stephen P, Wilson, Chick C, Cowan, John A
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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