Synthesis and Structure of [PPh4]3[Cr(Te4)3]·DMF:  The First Tris(tetratelluride) Complex

Synthesis and Structure of [PPh4]3[Cr(Te4)3]·DMF:  The First Tris(tetratelluride) Complex

The compound [PPh4]3[Cr(Te4)3]·DMF has been synthesized from the reaction of Cr(CO)6 with a polytelluride solution in dimethylformamide at 100 °C. The compound has been characterized by 125Te NMR and single-crystal X-ray diffraction techniques. The compound crystallizes in the triclinic space group...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Inorganic chemistry 2002-02, Vol.41 (3), p.450-451
Hauptverfasser: Sekar, Perumal, Ibers, James A
Format: Artikel
Sprache:eng
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
container_end_page 451
container_issue 3
container_start_page 450
container_title Inorganic chemistry
container_volume 41
creator Sekar, Perumal
Ibers, James A
description The compound [PPh4]3[Cr(Te4)3]·DMF has been synthesized from the reaction of Cr(CO)6 with a polytelluride solution in dimethylformamide at 100 °C. The compound has been characterized by 125Te NMR and single-crystal X-ray diffraction techniques. The compound crystallizes in the triclinic space group P1̄, with a = 12.991(3) Å, b = 14.782(3) Å, c = 24.628(5) Å, α = 90.63(3)°, β = 104.45(3)°, γ = 106.49(3)°, and Z = 2 (T = 153 K). The [Cr(Te4)3]3- anion consists of a Cr(III) center chelated by three Te4 2- ligands in a distorted octahedral environment. The anion has the Δλλλ (or Λδδδ) conformation.
doi_str_mv 10.1021/ic015585s
format Article
fullrecord <record><control><sourceid>acs_cross</sourceid><recordid>TN_cdi_crossref_primary_10_1021_ic015585s</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>b267670019</sourcerecordid><originalsourceid>FETCH-LOGICAL-a210t-1b88f2a8ffd2940e823e76c01dc85c635814cc7d770f40e802ca95cd5924486a3</originalsourceid><addsrcrecordid>eNptkM1Kw0AAhBdRsFYPvsFehPYQ3Z9ssvEmqVVpi4FGEGtZ1s2GpqZN2d1Ae_PqE3n3UXwSUyo9eZqB-RiYAeAco0uMCL4qFMKMcWYPQAszgjyG0fMhaCHUeBwE0TE4sXaOEIqoH7TA63izdDNtCwvlMoNjZ2rlaqNhlcNJksz8KZ3EppNqv0un31-9Uf_65-MTpjMN-4WxDqamsB2nnZFOl2Vtikx3YVwtVqVen4KjXJZWn_1pGzz1b9P43hs-3j3EN0NPEoych984z4nkeZ6RyEeaE6rDoBmSKc5UQBnHvlJhFoYo38aIKBkxlbGI-D4PJG2D7q5Xmcpao3OxMsVCmo3ASGxvEftbGtbbsYV1er0HpXkXQUhDJtJkLAZ0RIcvfCCShr_Y8VJZMa9qs2yW_NP7CwZYcKU</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>Synthesis and Structure of [PPh4]3[Cr(Te4)3]·DMF:  The First Tris(tetratelluride) Complex</title><source>ACS Publications</source><creator>Sekar, Perumal ; Ibers, James A</creator><creatorcontrib>Sekar, Perumal ; Ibers, James A</creatorcontrib><description>The compound [PPh4]3[Cr(Te4)3]·DMF has been synthesized from the reaction of Cr(CO)6 with a polytelluride solution in dimethylformamide at 100 °C. The compound has been characterized by 125Te NMR and single-crystal X-ray diffraction techniques. The compound crystallizes in the triclinic space group P1̄, with a = 12.991(3) Å, b = 14.782(3) Å, c = 24.628(5) Å, α = 90.63(3)°, β = 104.45(3)°, γ = 106.49(3)°, and Z = 2 (T = 153 K). The [Cr(Te4)3]3- anion consists of a Cr(III) center chelated by three Te4 2- ligands in a distorted octahedral environment. The anion has the Δλλλ (or Λδδδ) conformation.</description><identifier>ISSN: 0020-1669</identifier><identifier>EISSN: 1520-510X</identifier><identifier>DOI: 10.1021/ic015585s</identifier><language>eng</language><publisher>American Chemical Society</publisher><ispartof>Inorganic chemistry, 2002-02, Vol.41 (3), p.450-451</ispartof><rights>Copyright © 2002 American Chemical Society</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-a210t-1b88f2a8ffd2940e823e76c01dc85c635814cc7d770f40e802ca95cd5924486a3</citedby><cites>FETCH-LOGICAL-a210t-1b88f2a8ffd2940e823e76c01dc85c635814cc7d770f40e802ca95cd5924486a3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://pubs.acs.org/doi/pdf/10.1021/ic015585s$$EPDF$$P50$$Gacs$$H</linktopdf><linktohtml>$$Uhttps://pubs.acs.org/doi/10.1021/ic015585s$$EHTML$$P50$$Gacs$$H</linktohtml><link.rule.ids>314,780,784,2765,27076,27924,27925,56738,56788</link.rule.ids></links><search><creatorcontrib>Sekar, Perumal</creatorcontrib><creatorcontrib>Ibers, James A</creatorcontrib><title>Synthesis and Structure of [PPh4]3[Cr(Te4)3]·DMF:  The First Tris(tetratelluride) Complex</title><title>Inorganic chemistry</title><addtitle>Inorg. Chem</addtitle><description>The compound [PPh4]3[Cr(Te4)3]·DMF has been synthesized from the reaction of Cr(CO)6 with a polytelluride solution in dimethylformamide at 100 °C. The compound has been characterized by 125Te NMR and single-crystal X-ray diffraction techniques. The compound crystallizes in the triclinic space group P1̄, with a = 12.991(3) Å, b = 14.782(3) Å, c = 24.628(5) Å, α = 90.63(3)°, β = 104.45(3)°, γ = 106.49(3)°, and Z = 2 (T = 153 K). The [Cr(Te4)3]3- anion consists of a Cr(III) center chelated by three Te4 2- ligands in a distorted octahedral environment. The anion has the Δλλλ (or Λδδδ) conformation.</description><issn>0020-1669</issn><issn>1520-510X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2002</creationdate><recordtype>article</recordtype><recordid>eNptkM1Kw0AAhBdRsFYPvsFehPYQ3Z9ssvEmqVVpi4FGEGtZ1s2GpqZN2d1Ae_PqE3n3UXwSUyo9eZqB-RiYAeAco0uMCL4qFMKMcWYPQAszgjyG0fMhaCHUeBwE0TE4sXaOEIqoH7TA63izdDNtCwvlMoNjZ2rlaqNhlcNJksz8KZ3EppNqv0un31-9Uf_65-MTpjMN-4WxDqamsB2nnZFOl2Vtikx3YVwtVqVen4KjXJZWn_1pGzz1b9P43hs-3j3EN0NPEoych984z4nkeZ6RyEeaE6rDoBmSKc5UQBnHvlJhFoYo38aIKBkxlbGI-D4PJG2D7q5Xmcpao3OxMsVCmo3ASGxvEftbGtbbsYV1er0HpXkXQUhDJtJkLAZ0RIcvfCCShr_Y8VJZMa9qs2yW_NP7CwZYcKU</recordid><startdate>20020211</startdate><enddate>20020211</enddate><creator>Sekar, Perumal</creator><creator>Ibers, James A</creator><general>American Chemical Society</general><scope>BSCLL</scope><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20020211</creationdate><title>Synthesis and Structure of [PPh4]3[Cr(Te4)3]·DMF:  The First Tris(tetratelluride) Complex</title><author>Sekar, Perumal ; Ibers, James A</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a210t-1b88f2a8ffd2940e823e76c01dc85c635814cc7d770f40e802ca95cd5924486a3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2002</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Sekar, Perumal</creatorcontrib><creatorcontrib>Ibers, James A</creatorcontrib><collection>Istex</collection><collection>CrossRef</collection><jtitle>Inorganic chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Sekar, Perumal</au><au>Ibers, James A</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Synthesis and Structure of [PPh4]3[Cr(Te4)3]·DMF:  The First Tris(tetratelluride) Complex</atitle><jtitle>Inorganic chemistry</jtitle><addtitle>Inorg. Chem</addtitle><date>2002-02-11</date><risdate>2002</risdate><volume>41</volume><issue>3</issue><spage>450</spage><epage>451</epage><pages>450-451</pages><issn>0020-1669</issn><eissn>1520-510X</eissn><abstract>The compound [PPh4]3[Cr(Te4)3]·DMF has been synthesized from the reaction of Cr(CO)6 with a polytelluride solution in dimethylformamide at 100 °C. The compound has been characterized by 125Te NMR and single-crystal X-ray diffraction techniques. The compound crystallizes in the triclinic space group P1̄, with a = 12.991(3) Å, b = 14.782(3) Å, c = 24.628(5) Å, α = 90.63(3)°, β = 104.45(3)°, γ = 106.49(3)°, and Z = 2 (T = 153 K). The [Cr(Te4)3]3- anion consists of a Cr(III) center chelated by three Te4 2- ligands in a distorted octahedral environment. The anion has the Δλλλ (or Λδδδ) conformation.</abstract><pub>American Chemical Society</pub><doi>10.1021/ic015585s</doi><tpages>2</tpages></addata></record>
fulltext fulltext
identifier ISSN: 0020-1669
ispartof Inorganic chemistry, 2002-02, Vol.41 (3), p.450-451
issn 0020-1669
1520-510X
language eng
recordid cdi_crossref_primary_10_1021_ic015585s
source ACS Publications
title Synthesis and Structure of [PPh4]3[Cr(Te4)3]·DMF:  The First Tris(tetratelluride) Complex
url https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2024-12-25T17%3A21%3A46IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-acs_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Synthesis%20and%20Structure%20of%20%5BPPh4%5D3%5BCr(Te4)3%5D%C2%B7DMF:%E2%80%89%20The%20First%20Tris(tetratelluride)%20Complex&rft.jtitle=Inorganic%20chemistry&rft.au=Sekar,%20Perumal&rft.date=2002-02-11&rft.volume=41&rft.issue=3&rft.spage=450&rft.epage=451&rft.pages=450-451&rft.issn=0020-1669&rft.eissn=1520-510X&rft_id=info:doi/10.1021/ic015585s&rft_dat=%3Cacs_cross%3Eb267670019%3C/acs_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_id=info:pmid/&rfr_iscdi=true