Models for cytochrome P450 prosthetic heme alkylation. Reaction of diazoacetophenone with (tetraphenylporphyrinato)iron(II) chloride

The reaction of diazoacetophenone with (tetraphenylporphyrinato)iron(II) yields (N-(2-phenyl-2-oxoethyl)tetraphenylporphyrinato)iron(II) chloride. The structure of this product has been established by spectroscopic methods and by x-ray crystallography. The crystal structure shows that the first carb...

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Veröffentlicht in:	Inorg. Chem.; (United States) 1988-09, Vol.27 (18), p.3112-3117
Hauptverfasser:	Komives, Elizabeth A, Tew, David, Olmstead, Marilyn M, Ortiz de Montellano, Paul R
Format:	Artikel
Sprache:	eng
Schlagworte:	400201 - Chemical & Physicochemical Properties 400202 - Isotope Effects, Isotope Exchange, & Isotope Separation Bioinorganic chemistry CARBON 13 CARBON ISOTOPES CARBOXYLIC ACIDS Chemistry CHLORIDES CHLORINE COMPOUNDS CRYSTALLOGRAPHY DATA ELECTROMAGNETIC RADIATION EVEN-ODD NUCLEI Exact sciences and technology EXPERIMENTAL DATA HALIDES HALOGEN COMPOUNDS HETEROCYCLIC ACIDS HETEROCYCLIC COMPOUNDS INFORMATION Inorganic chemistry and origins of life INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY IONIZING RADIATIONS IRON CHLORIDES IRON COMPOUNDS ISOTOPE APPLICATIONS ISOTOPES LABELLED COMPOUNDS LIGHT NUCLEI MOLECULAR STRUCTURE NUCLEI NUMERICAL DATA ORGANIC ACIDS ORGANIC COMPOUNDS ORGANIC NITROGEN COMPOUNDS PORPHYRINS RADIATIONS SPECTROSCOPY STABLE ISOTOPES TRACER TECHNIQUES TRANSITION ELEMENT COMPOUNDS X RADIATION
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