Kinetics of electron-transfer reactions between transition-metal complexes and the methyl viologen radical cation
Kinetic data for the reactions between MV/sup /center dot/+/ and eight transition-metal complexes (of cobalt, ruthenium, chromium, and iron) and the uranyl ion were determined at pH 4 in 0.1 M perchlorate medium by pulse radiolysis. All the oxidants investigated are outer-sphere reagents with known...
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| Veröffentlicht in: | Inorg. Chem.; (United States) 1988-08, Vol.27 (17), p.2932-2934 |
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| container_issue | 17 |
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| container_title | Inorg. Chem.; (United States) |
| container_volume | 27 |
| creator | Howes, Kevin R Pippin, C. Greg Sullivan, James C Meisel, Dan Espenson, James H Bakac, Andreja |
| description | Kinetic data for the reactions between MV/sup /center dot/+/ and eight transition-metal complexes (of cobalt, ruthenium, chromium, and iron) and the uranyl ion were determined at pH 4 in 0.1 M perchlorate medium by pulse radiolysis. All the oxidants investigated are outer-sphere reagents with known standard reduction potentials and self-exchange rate constants. The measured rate constants are in agreement with those predicted by the Marcus theory after allowances are made for the diffusion control and electrostatics. 21 references, 2 figures, 1 table. |
| doi_str_mv | 10.1021/ic00290a008 |
| format | Article |
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Greg ; Sullivan, James C ; Meisel, Dan ; Espenson, James H ; Bakac, Andreja</creator><creatorcontrib>Howes, Kevin R ; Pippin, C. Greg ; Sullivan, James C ; Meisel, Dan ; Espenson, James H ; Bakac, Andreja ; Argonne National Lab., IL (USA)</creatorcontrib><description>Kinetic data for the reactions between MV/sup /center dot/+/ and eight transition-metal complexes (of cobalt, ruthenium, chromium, and iron) and the uranyl ion were determined at pH 4 in 0.1 M perchlorate medium by pulse radiolysis. All the oxidants investigated are outer-sphere reagents with known standard reduction potentials and self-exchange rate constants. The measured rate constants are in agreement with those predicted by the Marcus theory after allowances are made for the diffusion control and electrostatics. 21 references, 2 figures, 1 table.</description><identifier>ISSN: 0020-1669</identifier><identifier>EISSN: 1520-510X</identifier><identifier>DOI: 10.1021/ic00290a008</identifier><identifier>CODEN: INOCAJ</identifier><language>eng</language><publisher>Washington, DC: American Chemical Society</publisher><subject>400600 - Radiation Chemistry ; 400702 - Radiochemistry & Nuclear Chemistry- Properties of Radioactive Materials ; ACTINIDE COMPLEXES ; AZINES ; BIPYRIDINES ; CHEMICAL RADIATION EFFECTS ; CHEMICAL REACTIONS ; CHEMISTRY ; CHROMIUM COMPLEXES ; COBALT COMPLEXES ; COMPLEXES ; DECOMPOSITION ; ELECTRONS ; ELEMENTARY PARTICLES ; Exact sciences and technology ; FERMIONS ; HETEROCYCLIC COMPOUNDS ; Inorganic chemistry and origins of life ; IRON COMPLEXES ; IRRADIATION ; Kinetics and mechanism of reactions ; LEPTONS ; ORGANIC COMPOUNDS ; ORGANIC NITROGEN COMPOUNDS ; PULSED IRRADIATION ; PYRIDINES ; RADIATION CHEMISTRY ; RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCLEAR CHEMISTRY ; RADIATION EFFECTS ; RADIOLYSIS ; RUTHENIUM COMPLEXES ; TRANSITION ELEMENT COMPLEXES ; URANIUM COMPLEXES ; URANYL COMPLEXES</subject><ispartof>Inorg. 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Greg</creatorcontrib><creatorcontrib>Sullivan, James C</creatorcontrib><creatorcontrib>Meisel, Dan</creatorcontrib><creatorcontrib>Espenson, James H</creatorcontrib><creatorcontrib>Bakac, Andreja</creatorcontrib><creatorcontrib>Argonne National Lab., IL (USA)</creatorcontrib><title>Kinetics of electron-transfer reactions between transition-metal complexes and the methyl viologen radical cation</title><title>Inorg. Chem.; (United States)</title><addtitle>Inorg. Chem</addtitle><description>Kinetic data for the reactions between MV/sup /center dot/+/ and eight transition-metal complexes (of cobalt, ruthenium, chromium, and iron) and the uranyl ion were determined at pH 4 in 0.1 M perchlorate medium by pulse radiolysis. All the oxidants investigated are outer-sphere reagents with known standard reduction potentials and self-exchange rate constants. The measured rate constants are in agreement with those predicted by the Marcus theory after allowances are made for the diffusion control and electrostatics. 21 references, 2 figures, 1 table.</description><subject>400600 - Radiation Chemistry</subject><subject>400702 - Radiochemistry & Nuclear Chemistry- Properties of Radioactive Materials</subject><subject>ACTINIDE COMPLEXES</subject><subject>AZINES</subject><subject>BIPYRIDINES</subject><subject>CHEMICAL RADIATION EFFECTS</subject><subject>CHEMICAL REACTIONS</subject><subject>CHEMISTRY</subject><subject>CHROMIUM COMPLEXES</subject><subject>COBALT COMPLEXES</subject><subject>COMPLEXES</subject><subject>DECOMPOSITION</subject><subject>ELECTRONS</subject><subject>ELEMENTARY PARTICLES</subject><subject>Exact sciences and technology</subject><subject>FERMIONS</subject><subject>HETEROCYCLIC COMPOUNDS</subject><subject>Inorganic chemistry and origins of life</subject><subject>IRON COMPLEXES</subject><subject>IRRADIATION</subject><subject>Kinetics and mechanism of reactions</subject><subject>LEPTONS</subject><subject>ORGANIC COMPOUNDS</subject><subject>ORGANIC NITROGEN COMPOUNDS</subject><subject>PULSED IRRADIATION</subject><subject>PYRIDINES</subject><subject>RADIATION CHEMISTRY</subject><subject>RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCLEAR CHEMISTRY</subject><subject>RADIATION EFFECTS</subject><subject>RADIOLYSIS</subject><subject>RUTHENIUM COMPLEXES</subject><subject>TRANSITION ELEMENT COMPLEXES</subject><subject>URANIUM COMPLEXES</subject><subject>URANYL COMPLEXES</subject><issn>0020-1669</issn><issn>1520-510X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1988</creationdate><recordtype>article</recordtype><recordid>eNptkFFPFDEUhRuiiSvy5B9oDIkPZPR2ZtppHw1hwYBKIia-Nd3OLVucbZe2Cvx7ug4hPvh0k3O_c3PPIeQtgw8MWvbRW4BWgQGQe2TBeAsNZ_DzBVlUHRomhHpFXud8AwCq68WC3J77gMXbTKOjOKEtKYamJBOyw0QTGlt8DJmusNwhBvp35Xdas8FiJmrjZjvhPWZqwkjLGmnV1w8T_ePjFK-rJZnR2x1pdrY35KUzU8aDp7lPfixPro7Pmotvp5-PP100puOqNJ3oW9OO0pp-4GDboaYZnETFEZ0VzsqRCwErpVi3AjVKyftuGCR3jCs2rrp98m6-G3PxOltf0K5tDKFm1Fy1AqSs0NEM2RRzTuj0NvmNSQ-agd5Vqv-ptNKHM701uQZytQrr87NFKMWh7yrWzJjPBe-f1yb90mLoBq6vLr_rs2X75Vx9XerLyr-feWOzvom_U6i9_PeBR9DIkuA</recordid><startdate>19880801</startdate><enddate>19880801</enddate><creator>Howes, Kevin R</creator><creator>Pippin, C. Greg</creator><creator>Sullivan, James C</creator><creator>Meisel, Dan</creator><creator>Espenson, James H</creator><creator>Bakac, Andreja</creator><general>American Chemical Society</general><scope>BSCLL</scope><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>OTOTI</scope></search><sort><creationdate>19880801</creationdate><title>Kinetics of electron-transfer reactions between transition-metal complexes and the methyl viologen radical cation</title><author>Howes, Kevin R ; Pippin, C. Greg ; Sullivan, James C ; Meisel, Dan ; Espenson, James H ; Bakac, Andreja</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a359t-3642a2d8ca4750c271527f8e95eefc6fc8d5660b9913b09d885437785f1591db3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1988</creationdate><topic>400600 - Radiation Chemistry</topic><topic>400702 - Radiochemistry & Nuclear Chemistry- Properties of Radioactive Materials</topic><topic>ACTINIDE COMPLEXES</topic><topic>AZINES</topic><topic>BIPYRIDINES</topic><topic>CHEMICAL RADIATION EFFECTS</topic><topic>CHEMICAL REACTIONS</topic><topic>CHEMISTRY</topic><topic>CHROMIUM COMPLEXES</topic><topic>COBALT COMPLEXES</topic><topic>COMPLEXES</topic><topic>DECOMPOSITION</topic><topic>ELECTRONS</topic><topic>ELEMENTARY PARTICLES</topic><topic>Exact sciences and technology</topic><topic>FERMIONS</topic><topic>HETEROCYCLIC COMPOUNDS</topic><topic>Inorganic chemistry and origins of life</topic><topic>IRON COMPLEXES</topic><topic>IRRADIATION</topic><topic>Kinetics and mechanism of reactions</topic><topic>LEPTONS</topic><topic>ORGANIC COMPOUNDS</topic><topic>ORGANIC NITROGEN COMPOUNDS</topic><topic>PULSED IRRADIATION</topic><topic>PYRIDINES</topic><topic>RADIATION CHEMISTRY</topic><topic>RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCLEAR CHEMISTRY</topic><topic>RADIATION EFFECTS</topic><topic>RADIOLYSIS</topic><topic>RUTHENIUM COMPLEXES</topic><topic>TRANSITION ELEMENT COMPLEXES</topic><topic>URANIUM COMPLEXES</topic><topic>URANYL COMPLEXES</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Howes, Kevin R</creatorcontrib><creatorcontrib>Pippin, C. Greg</creatorcontrib><creatorcontrib>Sullivan, James C</creatorcontrib><creatorcontrib>Meisel, Dan</creatorcontrib><creatorcontrib>Espenson, James H</creatorcontrib><creatorcontrib>Bakac, Andreja</creatorcontrib><creatorcontrib>Argonne National Lab., IL (USA)</creatorcontrib><collection>Istex</collection><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>OSTI.GOV</collection><jtitle>Inorg. Chem.; (United States)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Howes, Kevin R</au><au>Pippin, C. Greg</au><au>Sullivan, James C</au><au>Meisel, Dan</au><au>Espenson, James H</au><au>Bakac, Andreja</au><aucorp>Argonne National Lab., IL (USA)</aucorp><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Kinetics of electron-transfer reactions between transition-metal complexes and the methyl viologen radical cation</atitle><jtitle>Inorg. Chem.; (United States)</jtitle><addtitle>Inorg. Chem</addtitle><date>1988-08-01</date><risdate>1988</risdate><volume>27</volume><issue>17</issue><spage>2932</spage><epage>2934</epage><pages>2932-2934</pages><issn>0020-1669</issn><eissn>1520-510X</eissn><coden>INOCAJ</coden><abstract>Kinetic data for the reactions between MV/sup /center dot/+/ and eight transition-metal complexes (of cobalt, ruthenium, chromium, and iron) and the uranyl ion were determined at pH 4 in 0.1 M perchlorate medium by pulse radiolysis. All the oxidants investigated are outer-sphere reagents with known standard reduction potentials and self-exchange rate constants. The measured rate constants are in agreement with those predicted by the Marcus theory after allowances are made for the diffusion control and electrostatics. 21 references, 2 figures, 1 table.</abstract><cop>Washington, DC</cop><pub>American Chemical Society</pub><doi>10.1021/ic00290a008</doi><tpages>3</tpages></addata></record> |
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| ispartof | Inorg. Chem.; (United States), 1988-08, Vol.27 (17), p.2932-2934 |
| issn | 0020-1669 1520-510X |
| language | eng |
| recordid | cdi_crossref_primary_10_1021_ic00290a008 |
| source | American Chemical Society Journals |
| subjects | 400600 - Radiation Chemistry 400702 - Radiochemistry & Nuclear Chemistry- Properties of Radioactive Materials ACTINIDE COMPLEXES AZINES BIPYRIDINES CHEMICAL RADIATION EFFECTS CHEMICAL REACTIONS CHEMISTRY CHROMIUM COMPLEXES COBALT COMPLEXES COMPLEXES DECOMPOSITION ELECTRONS ELEMENTARY PARTICLES Exact sciences and technology FERMIONS HETEROCYCLIC COMPOUNDS Inorganic chemistry and origins of life IRON COMPLEXES IRRADIATION Kinetics and mechanism of reactions LEPTONS ORGANIC COMPOUNDS ORGANIC NITROGEN COMPOUNDS PULSED IRRADIATION PYRIDINES RADIATION CHEMISTRY RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCLEAR CHEMISTRY RADIATION EFFECTS RADIOLYSIS RUTHENIUM COMPLEXES TRANSITION ELEMENT COMPLEXES URANIUM COMPLEXES URANYL COMPLEXES |
| title | Kinetics of electron-transfer reactions between transition-metal complexes and the methyl viologen radical cation |
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