Novel synthesis of reduced mixed-valence molybdenum and tungsten complexes by electrochemical oxidation of the seven-coordinate complexes MX(S2)(R2dtc)2 (M = Mo, X = O; M = W, X = O, S; R = alkyl; dtc = dithiocarbamate)

Novel synthesis of reduced mixed-valence molybdenum and tungsten complexes by electrochemical oxidation of the seven-coordinate complexes MX(S2)(R2dtc)2 (M = Mo, X = O; M = W, X = O, S; R = alkyl; dtc = dithiocarbamate)

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Veröffentlicht in:Inorganic chemistry 1988-03, Vol.27 (6), p.978-985
Hauptverfasser: Bond, A. M, Broomhead, J. A, Hollenkamp, A. F
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Sprache:eng
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Chemistry
Electrochemistry
Exact sciences and technology
General and physical chemistry
Kinetics and mechanism of reactions
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container_end_page 985
container_issue 6
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container_title Inorganic chemistry
container_volume 27
creator Bond, A. M
Broomhead, J. A
Hollenkamp, A. F
description
doi_str_mv 10.1021/ic00279a008
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subjects Chemistry
Electrochemistry
Exact sciences and technology
General and physical chemistry
Kinetics and mechanism of reactions
title Novel synthesis of reduced mixed-valence molybdenum and tungsten complexes by electrochemical oxidation of the seven-coordinate complexes MX(S2)(R2dtc)2 (M = Mo, X = O; M = W, X = O, S; R = alkyl; dtc = dithiocarbamate)
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