Kinetics and mechanisms of electron transfer between blue copper proteins and electronically excited chromium and ruthenium polypyridine complexes

The kinetics of the quenching of the long-lived excited states of CrL/sub 3//sup 3 +/ and RuL/sub 3//sup 2 +/ complexes (L is 1,10-phenanthroline and 2,2'-bipyridine or substituted derivatives) by the copper proteins plastocyanin, azurin, and stellacyanin have been studied in aqueous solution....

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