Ethanol oxidation by chromium(III) complexes of chloranilic acid. Spectroscopic, electrochemical, magnetic, and chromatographic studies of chloranilate semiquinone-bridged polynuclear chromium ions

The oxidation of ethanol by chloroanilic acid (H/sub 2/CA/sub ox/; 2,5-dihydroxy-3,6-dichlorobenzoquinone), catalyzed by Cr(III), has been reexamined. Rate and spectrophotometric studies showed that a binuclear complex of the form Cr/sub 2/(CA/sub ox/)/sup 4 +/ is the most reactive catalyst species;...

Ausführliche Beschreibung

Gespeichert in:

Bibliographische Detailangaben
Veröffentlicht in:	Inorg. Chem.; (United States) 1985-01, Vol.24 (2), p.153-159
Hauptverfasser:	Johnston, Randy F, Holwerda, Robert A
Format:	Artikel
Sprache:	eng
Schlagworte:	30 DIRECT ENERGY CONVERSION 300505 - Fuel Cells- Electrochemistry, Mass Transfer & Thermodynamics ALCOHOLS AQUEOUS SOLUTIONS AROMATICS BENZOQUINONES CATALYSIS CATALYSTS CATALYTIC EFFECTS CATIONS CHARGED PARTICLES CHEMICAL REACTION KINETICS CHEMICAL REACTIONS Chemistry CHLORANILIC ACID CHROMATOGRAPHY CHROMIUM CHROMIUM COMPLEXES COMPLEXES DATA DISPERSIONS ELECTRON SPIN RESONANCE ELEMENTS ETHANOL Exact sciences and technology EXPERIMENTAL DATA HYDROXY COMPOUNDS INFORMATION ION EXCHANGE CHROMATOGRAPHY IONS KINETICS Kinetics and mechanisms MAGNETIC PROPERTIES MAGNETIC RESONANCE MAGNETIC SUSCEPTIBILITY METALS MIXTURES NUMERICAL DATA Organic chemistry ORGANIC COMPOUNDS ORGANIC OXYGEN COMPOUNDS OXIDATION PHYSICAL PROPERTIES QUINONES REACTION KINETICS Reactivity and mechanisms RESONANCE SEPARATION PROCESSES SOLUTIONS SPECTROPHOTOMETRY TRANSITION ELEMENT COMPLEXES TRANSITION ELEMENTS VOLTAMETRY
Online-Zugang:	Volltext
Tags:	Tag hinzufügen Keine Tags, Fügen Sie den ersten Tag hinzu!

Schreiben Sie den ersten Kommentar!