Complexation of zinc tetraphenylporphyrin by adsorbed poly(4-vinylpyridine): equilibrium studies
Equilibrium constants have been measured for the reversible complexation of zinc tetraphenylporphyrin with poly(4-vinylpyridine) both in solution and in a system in which the polymer had been adsorbed onto fused silica. The complexation of the porphyrin with adsorbed polymer follows the behavior exp...
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| Veröffentlicht in: | Inorg. Chem.; (United States) 1983-10, Vol.22 (21), p.3050-3053 |
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| creator | Becker, D. Scott Hayes, R. G |
| description | Equilibrium constants have been measured for the reversible complexation of zinc tetraphenylporphyrin with poly(4-vinylpyridine) both in solution and in a system in which the polymer had been adsorbed onto fused silica. The complexation of the porphyrin with adsorbed polymer follows the behavior expected for reversible complexation at independent sites (so-called Langmuir-type isotherm). The equilibrium constant for complexation to the polymer in solution is somewhat smaller than that for complexation to pyridine, but the equivalent quantity for complexation to the polymer adsorbed onto silica is very large. 7 figures. |
| doi_str_mv | 10.1021/ic00163a014 |
| format | Article |
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Scott ; Hayes, R. G</creator><creatorcontrib>Becker, D. Scott ; Hayes, R. G ; Univ. of Notre Dame, South Bend, IN</creatorcontrib><description>Equilibrium constants have been measured for the reversible complexation of zinc tetraphenylporphyrin with poly(4-vinylpyridine) both in solution and in a system in which the polymer had been adsorbed onto fused silica. The complexation of the porphyrin with adsorbed polymer follows the behavior expected for reversible complexation at independent sites (so-called Langmuir-type isotherm). The equilibrium constant for complexation to the polymer in solution is somewhat smaller than that for complexation to pyridine, but the equivalent quantity for complexation to the polymer adsorbed onto silica is very large. 7 figures.</description><identifier>ISSN: 0020-1669</identifier><identifier>EISSN: 1520-510X</identifier><identifier>DOI: 10.1021/ic00163a014</identifier><identifier>CODEN: INOCAJ</identifier><language>eng</language><publisher>Washington, DC: American Chemical Society</publisher><subject>140505 - Solar Energy Conversion- Photochemical, Photobiological, & Thermochemical Conversion- (1980-) ; 360402 - Polymers & Plastics- Structure & Phase Studies- (-1987) ; 400201 - Chemical & Physicochemical Properties ; ADSORPTION ISOTHERMS ; AROMATICS ; AZINES ; BENZENE ; Bioinorganic chemistry ; CHALCOGENIDES ; CHEMICAL REACTIONS ; Chemistry ; COMPLEXES ; DATA ; EQUILIBRIUM ; Exact sciences and technology ; EXPERIMENTAL DATA ; HETEROCYCLIC COMPOUNDS ; HYDROCARBONS ; INFORMATION ; Inorganic chemistry and origins of life ; INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY ; ISOTHERM ; MATERIALS SCIENCE ; METHYLENE CHLORIDE ; MINERALS ; NUMERICAL DATA ; ORGANIC CHLORINE COMPOUNDS ; ORGANIC COMPOUNDS ; ORGANIC HALOGEN COMPOUNDS ; ORGANIC NITROGEN COMPOUNDS ; ORGANIC POLYMERS ; ORGANIC SOLVENTS ; OXIDE MINERALS ; OXIDES ; OXYGEN COMPOUNDS ; POLYMERS ; PYRIDINES ; SAMPLE PREPARATION ; SILICA ; SILICON COMPOUNDS ; SILICON OXIDES ; SOLAR ENERGY ; SOLVENTS ; SORPTIVE PROPERTIES ; SPECTRA ; SURFACE PROPERTIES ; THERMODYNAMIC ACTIVITY ; ULTRAVIOLET SPECTRA ; VISIBLE SPECTRA ; ZINC COMPLEXES</subject><ispartof>Inorg. Chem.; (United States), 1983-10, Vol.22 (21), p.3050-3053</ispartof><rights>1984 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-a359t-b0924f3ce76fc47924d2cef12ba85f10699e4ca75ad3589f122dab44e6d58e5d3</citedby></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://pubs.acs.org/doi/pdf/10.1021/ic00163a014$$EPDF$$P50$$Gacs$$H</linktopdf><linktohtml>$$Uhttps://pubs.acs.org/doi/10.1021/ic00163a014$$EHTML$$P50$$Gacs$$H</linktohtml><link.rule.ids>314,776,780,881,2752,27053,27901,27902,56713,56763</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=9408307$$DView record in Pascal Francis$$Hfree_for_read</backlink><backlink>$$Uhttps://www.osti.gov/biblio/5054826$$D View this record in Osti.gov$$Hfree_for_read</backlink></links><search><creatorcontrib>Becker, D. Scott</creatorcontrib><creatorcontrib>Hayes, R. G</creatorcontrib><creatorcontrib>Univ. of Notre Dame, South Bend, IN</creatorcontrib><title>Complexation of zinc tetraphenylporphyrin by adsorbed poly(4-vinylpyridine): equilibrium studies</title><title>Inorg. Chem.; (United States)</title><addtitle>Inorg. Chem</addtitle><description>Equilibrium constants have been measured for the reversible complexation of zinc tetraphenylporphyrin with poly(4-vinylpyridine) both in solution and in a system in which the polymer had been adsorbed onto fused silica. The complexation of the porphyrin with adsorbed polymer follows the behavior expected for reversible complexation at independent sites (so-called Langmuir-type isotherm). The equilibrium constant for complexation to the polymer in solution is somewhat smaller than that for complexation to pyridine, but the equivalent quantity for complexation to the polymer adsorbed onto silica is very large. 7 figures.</description><subject>140505 - Solar Energy Conversion- Photochemical, Photobiological, & Thermochemical Conversion- (1980-)</subject><subject>360402 - Polymers & Plastics- Structure & Phase Studies- (-1987)</subject><subject>400201 - Chemical & Physicochemical Properties</subject><subject>ADSORPTION ISOTHERMS</subject><subject>AROMATICS</subject><subject>AZINES</subject><subject>BENZENE</subject><subject>Bioinorganic chemistry</subject><subject>CHALCOGENIDES</subject><subject>CHEMICAL REACTIONS</subject><subject>Chemistry</subject><subject>COMPLEXES</subject><subject>DATA</subject><subject>EQUILIBRIUM</subject><subject>Exact sciences and technology</subject><subject>EXPERIMENTAL DATA</subject><subject>HETEROCYCLIC COMPOUNDS</subject><subject>HYDROCARBONS</subject><subject>INFORMATION</subject><subject>Inorganic chemistry and origins of life</subject><subject>INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY</subject><subject>ISOTHERM</subject><subject>MATERIALS SCIENCE</subject><subject>METHYLENE CHLORIDE</subject><subject>MINERALS</subject><subject>NUMERICAL DATA</subject><subject>ORGANIC CHLORINE COMPOUNDS</subject><subject>ORGANIC COMPOUNDS</subject><subject>ORGANIC HALOGEN COMPOUNDS</subject><subject>ORGANIC NITROGEN COMPOUNDS</subject><subject>ORGANIC POLYMERS</subject><subject>ORGANIC SOLVENTS</subject><subject>OXIDE MINERALS</subject><subject>OXIDES</subject><subject>OXYGEN COMPOUNDS</subject><subject>POLYMERS</subject><subject>PYRIDINES</subject><subject>SAMPLE PREPARATION</subject><subject>SILICA</subject><subject>SILICON COMPOUNDS</subject><subject>SILICON OXIDES</subject><subject>SOLAR ENERGY</subject><subject>SOLVENTS</subject><subject>SORPTIVE PROPERTIES</subject><subject>SPECTRA</subject><subject>SURFACE PROPERTIES</subject><subject>THERMODYNAMIC ACTIVITY</subject><subject>ULTRAVIOLET SPECTRA</subject><subject>VISIBLE SPECTRA</subject><subject>ZINC COMPLEXES</subject><issn>0020-1669</issn><issn>1520-510X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1983</creationdate><recordtype>article</recordtype><recordid>eNpt0F9r1TAYBvAgCjvOXe0LFBk4kW5v2vxpvHMHp8LAMad4F9Mk5WTrSbokR1Y_vRmV4cWukvD83pfwIHSI4QRDg0-dBsCsVYDJM7TCtIGaYvj5HK0Ayh0zJvbQy5RuAEC0hK3Qr3XYTqO9V9kFX4Wh-uO8rrLNUU0b6-dxCnHazNH5qp8rZVKIvTXVFMb5mNS_3YMoqXHevn1f2budG10f3W5bpbwzzqZX6MWgxmQP_p376Pv5x-v15_ri66cv6w8XtWqpyHUPoiFDqy1ngya8PEyj7YCbXnV0wMCEsEQrTpVpaSdK0BjVE2KZoZ2lpt1Hr5e9IWUnk3bZ6o0O3ludJQVKuoYV9G5BOoaUoh3kFN1WxVlikA8Nyv8aLPpo0ZNKWo1DVF679DgiCHQt8MLqhbmU7f1jrOKtZLzlVF5ffpOcCX6Gf3B5VfybxSud5E3YRV96efIDfwGpVo1f</recordid><startdate>19831001</startdate><enddate>19831001</enddate><creator>Becker, D. Scott</creator><creator>Hayes, R. G</creator><general>American Chemical Society</general><scope>BSCLL</scope><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>OTOTI</scope></search><sort><creationdate>19831001</creationdate><title>Complexation of zinc tetraphenylporphyrin by adsorbed poly(4-vinylpyridine): equilibrium studies</title><author>Becker, D. Scott ; Hayes, R. G</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a359t-b0924f3ce76fc47924d2cef12ba85f10699e4ca75ad3589f122dab44e6d58e5d3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1983</creationdate><topic>140505 - Solar Energy Conversion- Photochemical, Photobiological, & Thermochemical Conversion- (1980-)</topic><topic>360402 - Polymers & Plastics- Structure & Phase Studies- (-1987)</topic><topic>400201 - Chemical & Physicochemical Properties</topic><topic>ADSORPTION ISOTHERMS</topic><topic>AROMATICS</topic><topic>AZINES</topic><topic>BENZENE</topic><topic>Bioinorganic chemistry</topic><topic>CHALCOGENIDES</topic><topic>CHEMICAL REACTIONS</topic><topic>Chemistry</topic><topic>COMPLEXES</topic><topic>DATA</topic><topic>EQUILIBRIUM</topic><topic>Exact sciences and technology</topic><topic>EXPERIMENTAL DATA</topic><topic>HETEROCYCLIC COMPOUNDS</topic><topic>HYDROCARBONS</topic><topic>INFORMATION</topic><topic>Inorganic chemistry and origins of life</topic><topic>INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY</topic><topic>ISOTHERM</topic><topic>MATERIALS SCIENCE</topic><topic>METHYLENE CHLORIDE</topic><topic>MINERALS</topic><topic>NUMERICAL DATA</topic><topic>ORGANIC CHLORINE COMPOUNDS</topic><topic>ORGANIC COMPOUNDS</topic><topic>ORGANIC HALOGEN COMPOUNDS</topic><topic>ORGANIC NITROGEN COMPOUNDS</topic><topic>ORGANIC POLYMERS</topic><topic>ORGANIC SOLVENTS</topic><topic>OXIDE MINERALS</topic><topic>OXIDES</topic><topic>OXYGEN COMPOUNDS</topic><topic>POLYMERS</topic><topic>PYRIDINES</topic><topic>SAMPLE PREPARATION</topic><topic>SILICA</topic><topic>SILICON COMPOUNDS</topic><topic>SILICON OXIDES</topic><topic>SOLAR ENERGY</topic><topic>SOLVENTS</topic><topic>SORPTIVE PROPERTIES</topic><topic>SPECTRA</topic><topic>SURFACE PROPERTIES</topic><topic>THERMODYNAMIC ACTIVITY</topic><topic>ULTRAVIOLET SPECTRA</topic><topic>VISIBLE SPECTRA</topic><topic>ZINC COMPLEXES</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Becker, D. Scott</creatorcontrib><creatorcontrib>Hayes, R. G</creatorcontrib><creatorcontrib>Univ. of Notre Dame, South Bend, IN</creatorcontrib><collection>Istex</collection><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>OSTI.GOV</collection><jtitle>Inorg. Chem.; (United States)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Becker, D. Scott</au><au>Hayes, R. G</au><aucorp>Univ. of Notre Dame, South Bend, IN</aucorp><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Complexation of zinc tetraphenylporphyrin by adsorbed poly(4-vinylpyridine): equilibrium studies</atitle><jtitle>Inorg. Chem.; (United States)</jtitle><addtitle>Inorg. Chem</addtitle><date>1983-10-01</date><risdate>1983</risdate><volume>22</volume><issue>21</issue><spage>3050</spage><epage>3053</epage><pages>3050-3053</pages><issn>0020-1669</issn><eissn>1520-510X</eissn><coden>INOCAJ</coden><abstract>Equilibrium constants have been measured for the reversible complexation of zinc tetraphenylporphyrin with poly(4-vinylpyridine) both in solution and in a system in which the polymer had been adsorbed onto fused silica. The complexation of the porphyrin with adsorbed polymer follows the behavior expected for reversible complexation at independent sites (so-called Langmuir-type isotherm). The equilibrium constant for complexation to the polymer in solution is somewhat smaller than that for complexation to pyridine, but the equivalent quantity for complexation to the polymer adsorbed onto silica is very large. 7 figures.</abstract><cop>Washington, DC</cop><pub>American Chemical Society</pub><doi>10.1021/ic00163a014</doi><tpages>4</tpages></addata></record> |
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| ispartof | Inorg. Chem.; (United States), 1983-10, Vol.22 (21), p.3050-3053 |
| issn | 0020-1669 1520-510X |
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| source | ACS Publications |
| subjects | 140505 - Solar Energy Conversion- Photochemical, Photobiological, & Thermochemical Conversion- (1980-) 360402 - Polymers & Plastics- Structure & Phase Studies- (-1987) 400201 - Chemical & Physicochemical Properties ADSORPTION ISOTHERMS AROMATICS AZINES BENZENE Bioinorganic chemistry CHALCOGENIDES CHEMICAL REACTIONS Chemistry COMPLEXES DATA EQUILIBRIUM Exact sciences and technology EXPERIMENTAL DATA HETEROCYCLIC COMPOUNDS HYDROCARBONS INFORMATION Inorganic chemistry and origins of life INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY ISOTHERM MATERIALS SCIENCE METHYLENE CHLORIDE MINERALS NUMERICAL DATA ORGANIC CHLORINE COMPOUNDS ORGANIC COMPOUNDS ORGANIC HALOGEN COMPOUNDS ORGANIC NITROGEN COMPOUNDS ORGANIC POLYMERS ORGANIC SOLVENTS OXIDE MINERALS OXIDES OXYGEN COMPOUNDS POLYMERS PYRIDINES SAMPLE PREPARATION SILICA SILICON COMPOUNDS SILICON OXIDES SOLAR ENERGY SOLVENTS SORPTIVE PROPERTIES SPECTRA SURFACE PROPERTIES THERMODYNAMIC ACTIVITY ULTRAVIOLET SPECTRA VISIBLE SPECTRA ZINC COMPLEXES |
| title | Complexation of zinc tetraphenylporphyrin by adsorbed poly(4-vinylpyridine): equilibrium studies |
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