Reinvestigation of the reaction of tert-butyllithium with uranium tetrachloride: formation of catalytically active uranium(III) hydride complexes

The reaction of UCl/sub 4/ with t-C/sub 4/H/sub 9/Li in alkane solvents has been reinvestigated in detail by quantitative collection and identification of gaseous products and by spectral, analytical, and chemical characterization of the solid uranium products. Treatment of UCl/sub 4/ with 4 equiv o...

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