New synthetic routes to B-halogenated derivatives of cobalt dicarbollide

The synthesis and characterization of the B(10),B(10{prime})-dihalogenated metallocarboranes [Co(10-X-7,8-C{sub 2}B{sub 9}H{sub 10}){sub 2}]{sup {minus}}, where X = Cl or Br, are reported. The C{sub 2h} symmetry of these diamagnetic Co(III) compounds allows straightforward identification using {sup...

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Veröffentlicht in:	Inorganic Chemistry 1995-10, Vol.34 (21), p.5215-5219
Hauptverfasser:	Hurlburt, Paul K, Miller, Rebecca L, Abney, Kent D, Foreman, Trudi M, Butcher, Raymond J, Kinkhead, Scott A
Format:	Artikel
Sprache:	eng
Schlagworte:	40 CHEMISTRY BROMINE COMPOUNDS CARBORANES CHEMICAL PREPARATION CHLORINE COMPOUNDS COBALT COMPOUNDS CRYSTAL STRUCTURE MONOCLINIC LATTICES NUCLEAR MAGNETIC RESONANCE X-RAY DIFFRACTION
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