Synthesis and Characterization of Lanthanide(III) (La, Gd, Yb, Y) Disalicylidene-1,2-phenylenediamine (H2dsp) Schiff-Base Complexes

Novel rare earth (III) disalicylidene-1,2-phenylenediamine(H{sub 2}dsp) complexes with the formula M[Ln(dsp){sub 2}] (M = Li, Na, K, Cs) were prepared. UV-visible absorption and NMR were used to study the disproportionation equilibrium for these complexes in DMSO. Structures for these complexes are...

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Veröffentlicht in:	Inorganic Chemistry 1994-11, Vol.33 (23), p.5195-5202
Hauptverfasser:	Chen, Huiyong, Archer, Ronald D
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Sprache:	eng
Schlagworte:	40 CHEMISTRY ABSORPTION SPECTROSCOPY AMINES CHEMICAL PREPARATION GADOLINIUM COMPLEXES LANTHANUM COMPLEXES NUCLEAR MAGNETIC RESONANCE STRUCTURAL CHEMICAL ANALYSIS YTTERBIUM COMPLEXES YTTRIUM COMPLEXES
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container_title	Inorganic Chemistry
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creator	Chen, Huiyong Archer, Ronald D
description	Novel rare earth (III) disalicylidene-1,2-phenylenediamine(H{sub 2}dsp) complexes with the formula M[Ln(dsp){sub 2}] (M = Li, Na, K, Cs) were prepared. UV-visible absorption and NMR were used to study the disproportionation equilibrium for these complexes in DMSO. Structures for these complexes are suggested.
doi_str_mv	10.1021/ic00101a010
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UV-visible absorption and NMR were used to study the disproportionation equilibrium for these complexes in DMSO. 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Chem</addtitle><description>Novel rare earth (III) disalicylidene-1,2-phenylenediamine(H{sub 2}dsp) complexes with the formula M[Ln(dsp){sub 2}] (M = Li, Na, K, Cs) were prepared. UV-visible absorption and NMR were used to study the disproportionation equilibrium for these complexes in DMSO. Structures for these complexes are suggested.</description><subject>40 CHEMISTRY</subject><subject>ABSORPTION SPECTROSCOPY</subject><subject>AMINES</subject><subject>CHEMICAL PREPARATION</subject><subject>GADOLINIUM COMPLEXES</subject><subject>LANTHANUM COMPLEXES</subject><subject>NUCLEAR MAGNETIC RESONANCE</subject><subject>STRUCTURAL CHEMICAL ANALYSIS</subject><subject>YTTERBIUM COMPLEXES</subject><subject>YTTRIUM COMPLEXES</subject><issn>0020-1669</issn><issn>1520-510X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1994</creationdate><recordtype>article</recordtype><recordid>eNpt0EtrGzEQAGARWoib9pQ_oJ5qU2870r6PsdskBkNd7EKSixjNSqzStdasNhD32j9eFZfSQw_zgo-BGcYuBXwQIMVHRwACBMZ0xiYil5DkAu5esAlA7EVR1OfsVQiPAFCnWTFhP7dHP7YmuMDRN3zZ4oA0msH9wNH1nveWrzEK9K4x09VqNePTNc75TTPn9zrGjH9yATtHxy4KbxIxl8mhNf7YxalxuHfe8OmtbMJhxrfUOmuTBQbDl_3-0JlnE16zlxa7YN78qRfs2_Xn3fI2WX-5WS2v1gnKTI5JWWmw2tQmE6aSJBG1JqRCVxqJNKKFJre6sGkjckJREthSVE2VYp3lqNML9va0tw-jU4HcaKil3ntDo8ok1DVE8_5kaOhDGIxVh8HtcTgqAer3j9U_P446OWkXRvP8l-LwXRVlWuZqt9mqh-tys_u62KhF9O9OHimox_5p8PHe_27-BccNisY</recordid><startdate>19941101</startdate><enddate>19941101</enddate><creator>Chen, Huiyong</creator><creator>Archer, Ronald D</creator><general>American Chemical Society</general><scope>BSCLL</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>OTOTI</scope></search><sort><creationdate>19941101</creationdate><title>Synthesis and Characterization of Lanthanide(III) (La, Gd, Yb, Y) Disalicylidene-1,2-phenylenediamine (H2dsp) Schiff-Base Complexes</title><author>Chen, Huiyong ; Archer, Ronald D</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a242t-78b0fbe9e41e82c2aabbcac6b8baccbaaf0d5fb6f3d15ca17c0f718d83a945ab3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1994</creationdate><topic>40 CHEMISTRY</topic><topic>ABSORPTION SPECTROSCOPY</topic><topic>AMINES</topic><topic>CHEMICAL PREPARATION</topic><topic>GADOLINIUM COMPLEXES</topic><topic>LANTHANUM COMPLEXES</topic><topic>NUCLEAR MAGNETIC RESONANCE</topic><topic>STRUCTURAL CHEMICAL ANALYSIS</topic><topic>YTTERBIUM COMPLEXES</topic><topic>YTTRIUM COMPLEXES</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Chen, Huiyong</creatorcontrib><creatorcontrib>Archer, Ronald D</creatorcontrib><collection>Istex</collection><collection>CrossRef</collection><collection>OSTI.GOV</collection><jtitle>Inorganic Chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Chen, Huiyong</au><au>Archer, Ronald D</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Synthesis and Characterization of Lanthanide(III) (La, Gd, Yb, Y) Disalicylidene-1,2-phenylenediamine (H2dsp) Schiff-Base Complexes</atitle><jtitle>Inorganic Chemistry</jtitle><addtitle>Inorg. Chem</addtitle><date>1994-11-01</date><risdate>1994</risdate><volume>33</volume><issue>23</issue><spage>5195</spage><epage>5202</epage><pages>5195-5202</pages><issn>0020-1669</issn><eissn>1520-510X</eissn><abstract>Novel rare earth (III) disalicylidene-1,2-phenylenediamine(H{sub 2}dsp) complexes with the formula M[Ln(dsp){sub 2}] (M = Li, Na, K, Cs) were prepared. UV-visible absorption and NMR were used to study the disproportionation equilibrium for these complexes in DMSO. Structures for these complexes are suggested.</abstract><cop>United States</cop><pub>American Chemical Society</pub><doi>10.1021/ic00101a010</doi><tpages>8</tpages></addata></record>
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subjects	40 CHEMISTRY ABSORPTION SPECTROSCOPY AMINES CHEMICAL PREPARATION GADOLINIUM COMPLEXES LANTHANUM COMPLEXES NUCLEAR MAGNETIC RESONANCE STRUCTURAL CHEMICAL ANALYSIS YTTERBIUM COMPLEXES YTTRIUM COMPLEXES
title	Synthesis and Characterization of Lanthanide(III) (La, Gd, Yb, Y) Disalicylidene-1,2-phenylenediamine (H2dsp) Schiff-Base Complexes
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