Metal-Metal Multiply Bonded Complexes of Technetium. 1. Synthesis and Structural Characterization of Phosphine Complexes That Contain a Tc-Tc Multiple Bond

A series of triply metal-metal bonded ditechnetium(II) phosphine complexes with the general formula Tc{sub 2}Cl{sub 4}(PR{sub 3}){sub 4} (PR{sub 3} = PEt{sub 3}, PPr{sup n}{sub 3}, PMePh{sub 2}, PMe{sub 2}Ph) have been prepared from mononuclear Tc(IV) precursors and fully characterized. Two-electron...

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Veröffentlicht in:	Inorganic Chemistry 1994-05, Vol.33 (10), p.2257-2264
Hauptverfasser:	Burns, Carol J, Burrell, Anthony K, Cotton, F. Albert, Haefner, Steven C, Sattelberger, Alfred P
Format:	Artikel
Sprache:	eng
Schlagworte:	40 CHEMISTRY ABSORPTION SPECTROSCOPY CHEMICAL PREPARATION CHEMICAL REACTION YIELD ELECTRONIC STRUCTURE NUCLEAR MAGNETIC RESONANCE OXIDATION REDUCTION STRUCTURAL CHEMICAL ANALYSIS TECHNETIUM COMPLEXES
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