Synthesis and phosphorus-31 NMR spectroscopy of trinuclear, phosphido-bridged iridium and rhodium clusters. Crystal and molecular structures of [M3(.mu.-PPh2)3(CO)nL2] (M = Ir or Rh, n = 3, L2 = 1,2-bis(diphenylphosphino)methane; M = Ir, n = 5, L = tert-BuNC)

Synthesis and phosphorus-31 NMR spectroscopy of trinuclear, phosphido-bridged iridium and rhodium clusters. Crystal and molecular structures of [M3(.mu.-PPh2)3(CO)nL2] (M = Ir or Rh, n = 3, L2 = 1,2-bis(diphenylphosphino)methane; M = Ir, n = 5, L = tert-BuNC)

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Veröffentlicht in:Inorganic chemistry 1991-02, Vol.30 (3), p.396-402
Hauptverfasser: Berry, David E, Browning, Jane, Dehghan, Khashayar, Dixon, Keith R, Meanwell, Neil J, Phillips, Andrew J
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container_title Inorganic chemistry
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creator Berry, David E
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Dixon, Keith R
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title Synthesis and phosphorus-31 NMR spectroscopy of trinuclear, phosphido-bridged iridium and rhodium clusters. Crystal and molecular structures of [M3(.mu.-PPh2)3(CO)nL2] (M = Ir or Rh, n = 3, L2 = 1,2-bis(diphenylphosphino)methane; M = Ir, n = 5, L = tert-BuNC)
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