Thermodynamics of alcohol-alcohol mixtures. 1. A continuous linear association model for alcohol-alcohol solutions

An equation for the excess Gibbs energy of alcohol-alcohol solutions has been derived. The model used in the derivation is based on the hypothesis of a continuous linear association of both alcohol molecules. Expressions for the activity coefficients as well as for the heat of mixing are given. All...

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Veröffentlicht in:	Ind. Eng. Chem. Process Des. Dev.; (United States) 1984-01, Vol.23 (1), p.67-72
Hauptverfasser:	Pando, Concepcion, Renuncio, Juan A. R, Hanks, Richard W, Christensen, James J
Format:	Artikel
Sprache:	eng
Schlagworte:	400301 - Organic Chemistry- Chemical & Physicochemical Properties- (-1987) ALCOHOLS BINARY MIXTURES COMPARATIVE EVALUATIONS DISPERSIONS ENERGY ENTHALPY EQUATIONS EQUILIBRIUM FREE ENTHALPY HYDROXY COMPOUNDS INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY MATHEMATICAL MODELS MIXING HEAT MIXTURES ORGANIC COMPOUNDS PHYSICAL PROPERTIES THERMAL EQUILIBRIUM THERMODYNAMIC ACTIVITY THERMODYNAMIC PROPERTIES THERMODYNAMICS
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