Source identification of aromatic hydrocarbons in sediments using GC/MS
A method that may distinguish between input of polycyclic aromatic hydrocarbons (PAH) from petroleum and combustion sources is demonstrated on sediment samples. Selected series of aromatics (unsubstituted compounds and their C/sub 1/-C/sub 3/ alkyl homologues) are quantified by computerized GC/MS. T...
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| Veröffentlicht in: | Environ. Sci. Technol.; (United States) 1983-05, Vol.17 (5), p.282-286 |
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| container_title | Environ. Sci. Technol.; (United States) |
| container_volume | 17 |
| creator | Sporstol, Sigve Gjos, Nina Lichtenthaler, Rainer G Gustavsen, Kay O Urdal, Kjell Oreld, Froydis Skei, Jens |
| description | A method that may distinguish between input of polycyclic aromatic hydrocarbons (PAH) from petroleum and combustion sources is demonstrated on sediment samples. Selected series of aromatics (unsubstituted compounds and their C/sub 1/-C/sub 3/ alkyl homologues) are quantified by computerized GC/MS. The alkyl homologue distribution (AHD) within each series and the sum of components in each series relative to the sum of all components measured (relative amount of each aromatic series (RAA)) are graphically visualized. In combination these parameters give a first-order indication of the PAH source. Pyrene/fluoranthene AHD series appear to be especially sensitive as an indicator for detecting PAH from combustion sources. Interestingly the dibenzothiophene AHD series does not discriminate between crude oil and soot samples. The method is demonstrated on sediments from the North Sea and from Norwegian and Swedish fjords. |
| doi_str_mv | 10.1021/es00111a008 |
| format | Article |
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Selected series of aromatics (unsubstituted compounds and their C/sub 1/-C/sub 3/ alkyl homologues) are quantified by computerized GC/MS. The alkyl homologue distribution (AHD) within each series and the sum of components in each series relative to the sum of all components measured (relative amount of each aromatic series (RAA)) are graphically visualized. In combination these parameters give a first-order indication of the PAH source. Pyrene/fluoranthene AHD series appear to be especially sensitive as an indicator for detecting PAH from combustion sources. Interestingly the dibenzothiophene AHD series does not discriminate between crude oil and soot samples. 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Sci. Technol.; (United States)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Sporstol, Sigve</au><au>Gjos, Nina</au><au>Lichtenthaler, Rainer G</au><au>Gustavsen, Kay O</au><au>Urdal, Kjell</au><au>Oreld, Froydis</au><au>Skei, Jens</au><aucorp>Central Inst. for Industrial Research, Oslo, Norway</aucorp><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Source identification of aromatic hydrocarbons in sediments using GC/MS</atitle><jtitle>Environ. Sci. Technol.; (United States)</jtitle><addtitle>Environ. Sci. Technol</addtitle><date>1983-05</date><risdate>1983</risdate><volume>17</volume><issue>5</issue><spage>282</spage><epage>286</epage><pages>282-286</pages><issn>0013-936X</issn><eissn>1520-5851</eissn><abstract>A method that may distinguish between input of polycyclic aromatic hydrocarbons (PAH) from petroleum and combustion sources is demonstrated on sediment samples. Selected series of aromatics (unsubstituted compounds and their C/sub 1/-C/sub 3/ alkyl homologues) are quantified by computerized GC/MS. The alkyl homologue distribution (AHD) within each series and the sum of components in each series relative to the sum of all components measured (relative amount of each aromatic series (RAA)) are graphically visualized. In combination these parameters give a first-order indication of the PAH source. Pyrene/fluoranthene AHD series appear to be especially sensitive as an indicator for detecting PAH from combustion sources. Interestingly the dibenzothiophene AHD series does not discriminate between crude oil and soot samples. The method is demonstrated on sediments from the North Sea and from Norwegian and Swedish fjords.</abstract><cop>United States</cop><pub>American Chemical Society</pub><doi>10.1021/es00111a008</doi><tpages>5</tpages></addata></record> |
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| identifier | ISSN: 0013-936X |
| ispartof | Environ. Sci. Technol.; (United States), 1983-05, Vol.17 (5), p.282-286 |
| issn | 0013-936X 1520-5851 |
| language | eng |
| recordid | cdi_crossref_primary_10_1021_es00111a008 |
| source | American Chemical Society |
| subjects | 400104 - Spectral Procedures- (-1987) 520200 - Environment, Aquatic- Chemicals Monitoring & Transport- (-1989) AROMATICS ATLANTIC OCEAN CHEMICAL ANALYSIS CHROMATOGRAPHY ENVIRONMENTAL SCIENCES ESTUARIES EUROPE FIORDS GAS CHROMATOGRAPHY HYDROCARBONS INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY MASS SPECTROSCOPY NORTH SEA NORWAY ORGANIC COMPOUNDS POLLUTION SOURCES POLYCYCLIC AROMATIC HYDROCARBONS QUANTITATIVE CHEMICAL ANALYSIS SCANDINAVIA SEAS SEDIMENTS SEPARATION PROCESSES SPECTROSCOPY SURFACE WATERS SWEDEN WESTERN EUROPE |
| title | Source identification of aromatic hydrocarbons in sediments using GC/MS |
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