The impact of Metal–Ligand Cooperation in Hydrogenation of Carbon Dioxide Catalyzed by Ruthenium PNP Pincer

The metal–ligand cooperative activation of CO2 with pyridine-based ruthenium PNP pincer catalysts leads to pronounced inhibition of the activity in the catalytic CO2 hydrogenation to formic acid. The addition of water restores catalytic performance by activating alternative reaction pathways and lea...

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Veröffentlicht in:ACS catalysis 2013-11, Vol.3 (11), p.2522-2526
Hauptverfasser: Filonenko, Georgy A, Conley, Matthew P, Copéret, Christophe, Lutz, Martin, Hensen, Emiel J. M, Pidko, Evgeny A
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container_end_page 2526
container_issue 11
container_start_page 2522
container_title ACS catalysis
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creator Filonenko, Georgy A
Conley, Matthew P
Copéret, Christophe
Lutz, Martin
Hensen, Emiel J. M
Pidko, Evgeny A
description The metal–ligand cooperative activation of CO2 with pyridine-based ruthenium PNP pincer catalysts leads to pronounced inhibition of the activity in the catalytic CO2 hydrogenation to formic acid. The addition of water restores catalytic performance by activating alternative reaction pathways and leads to unprecedented Ru-catalyzed CO2 hydrogenation activity. The mechanism of the underlying chemical transformations is proposed on the basis of DFT calculations, kinetic experiments, and NMR reactivity studies.
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title The impact of Metal–Ligand Cooperation in Hydrogenation of Carbon Dioxide Catalyzed by Ruthenium PNP Pincer
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