Mechanistic Study of a Ru-Xantphos Catalyst for Tandem Alcohol Dehydrogenation and Reductive Aryl-Ether Cleavage

We employ density functional theory (DFT) calculations and kinetics measurements to understand the mechanism of a xantphos-containing molecular ruthenium catalyst acting on an alkyl aryl ether linkage similar to that found in lignin to produce acetophenone and phenol. The most favorable reaction pat...

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Veröffentlicht in:	ACS Catalysis 2013-05, Vol.3 (5), p.963-974
Hauptverfasser:	Chmely, Stephen C, Kim, Seonah, Ciesielski, Peter N, Jiménez-Osés, Gonzalo, Paton, Robert S, Beckham, Gregg T
Format:	Artikel
Sprache:	eng
Schlagworte:	BASIC BIOLOGICAL SCIENCES Bioenergy INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY
Online-Zugang:	Volltext
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