5‑Hydroxymethylfurfural Synthesis from Hexoses Is Autocatalytic

5‑Hydroxymethylfurfural Synthesis from Hexoses Is Autocatalytic

Many researchers and articles have reported the development of synthesis methods for 5-hydroxymethylfurfural, one of the top 12 biobased building blocks listed by the U.S. Department of Energy. The focus has especially been on the development of efficient catalytic systems for this synthesis. In con...

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Veröffentlicht in:ACS catalysis 2013-04, Vol.3 (4), p.760-763
Hauptverfasser: Ranoux, Adeline, Djanashvili, Kristina, Arends, Isabel W. C. E, Hanefeld, Ulf
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container_title ACS catalysis
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creator Ranoux, Adeline
Djanashvili, Kristina
Arends, Isabel W. C. E
Hanefeld, Ulf
description Many researchers and articles have reported the development of synthesis methods for 5-hydroxymethylfurfural, one of the top 12 biobased building blocks listed by the U.S. Department of Energy. The focus has especially been on the development of efficient catalytic systems for this synthesis. In contrast, we report here a process that does not require any added catalysts, yet leads to interesting yields and selectivities. Moreover, we demonstrate that the process is autocatalytic involving formic acid, the byproduct.
doi_str_mv 10.1021/cs400099a
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title 5‑Hydroxymethylfurfural Synthesis from Hexoses Is Autocatalytic
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