Processible and Thermally Stable Heterocyclic Polymers for Second-Order Nonlinear Optical Studies
Following up on our preliminary communication, we present in this paper a novel approach to synthesize processible, cross-linkable, and thermally stable heterocyclic polymers (polyoxazolidones) with nonlinear optical properties. A cross-linkable NLO chromophore was synthesized and transformed into a...
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| Veröffentlicht in: | Chemistry of materials 1996-11, Vol.8 (11), p.2681-2685 |
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| container_end_page | 2685 |
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| container_issue | 11 |
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| container_title | Chemistry of materials |
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| creator | Liang, Zhiyong Yang, Zhixin Sun, Shajing Wu, Bo Dalton, Larry R Garner, Sean M Kalluri, Srinath Chen, Antao Steier, William H |
| description | Following up on our preliminary communication, we present in this paper a novel approach to synthesize processible, cross-linkable, and thermally stable heterocyclic polymers (polyoxazolidones) with nonlinear optical properties. A cross-linkable NLO chromophore was synthesized and transformed into a prepolymer, which was easy to process and cross-link. After being efficiently poled and cured, the optical-quality films exhibited good nonlinearity and thermal stability. The stable, hardened lattice resulted from the formation of the heterocyclic ring. The details of synthesizing the cross-linked (trifunctional) and un-cross-linked (difunctional) heterocyclic polymers are presented. The effects of the processing conditions on the NLO properties are described. d 33 coefficients of 77 and 85 pm/V at the 1.06 μm fundamental wavelength for the cross-linked and un-cross-linked polymers were obtained, respectively. |
| doi_str_mv | 10.1021/cm960221x |
| format | Article |
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A cross-linkable NLO chromophore was synthesized and transformed into a prepolymer, which was easy to process and cross-link. After being efficiently poled and cured, the optical-quality films exhibited good nonlinearity and thermal stability. The stable, hardened lattice resulted from the formation of the heterocyclic ring. The details of synthesizing the cross-linked (trifunctional) and un-cross-linked (difunctional) heterocyclic polymers are presented. The effects of the processing conditions on the NLO properties are described. d 33 coefficients of 77 and 85 pm/V at the 1.06 μm fundamental wavelength for the cross-linked and un-cross-linked polymers were obtained, respectively.</description><identifier>ISSN: 0897-4756</identifier><identifier>EISSN: 1520-5002</identifier><identifier>DOI: 10.1021/cm960221x</identifier><language>eng</language><publisher>Washington, DC: American Chemical Society</publisher><subject>Applied sciences ; Electrical, magnetic and optical properties ; Exact sciences and technology ; Organic polymers ; Physicochemistry of polymers ; Properties and characterization</subject><ispartof>Chemistry of materials, 1996-11, Vol.8 (11), p.2681-2685</ispartof><rights>Copyright © 1996 American Chemical Society</rights><rights>1997 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-a324t-d40ed8f7d945ec7b334a21ad1d90186d5331d5ece9172e9d0fc6bc4f7fb8613e3</citedby><cites>FETCH-LOGICAL-a324t-d40ed8f7d945ec7b334a21ad1d90186d5331d5ece9172e9d0fc6bc4f7fb8613e3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://pubs.acs.org/doi/pdf/10.1021/cm960221x$$EPDF$$P50$$Gacs$$H</linktopdf><linktohtml>$$Uhttps://pubs.acs.org/doi/10.1021/cm960221x$$EHTML$$P50$$Gacs$$H</linktohtml><link.rule.ids>314,776,780,2752,27053,27901,27902,56713,56763</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=2506424$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Liang, Zhiyong</creatorcontrib><creatorcontrib>Yang, Zhixin</creatorcontrib><creatorcontrib>Sun, Shajing</creatorcontrib><creatorcontrib>Wu, Bo</creatorcontrib><creatorcontrib>Dalton, Larry R</creatorcontrib><creatorcontrib>Garner, Sean M</creatorcontrib><creatorcontrib>Kalluri, Srinath</creatorcontrib><creatorcontrib>Chen, Antao</creatorcontrib><creatorcontrib>Steier, William H</creatorcontrib><title>Processible and Thermally Stable Heterocyclic Polymers for Second-Order Nonlinear Optical Studies</title><title>Chemistry of materials</title><addtitle>Chem. 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The effects of the processing conditions on the NLO properties are described. d 33 coefficients of 77 and 85 pm/V at the 1.06 μm fundamental wavelength for the cross-linked and un-cross-linked polymers were obtained, respectively.</description><subject>Applied sciences</subject><subject>Electrical, magnetic and optical properties</subject><subject>Exact sciences and technology</subject><subject>Organic polymers</subject><subject>Physicochemistry of polymers</subject><subject>Properties and characterization</subject><issn>0897-4756</issn><issn>1520-5002</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1996</creationdate><recordtype>article</recordtype><recordid>eNptkEtLAzEUhYMoWKsL_0EWunAxmuc8lirWitUWWtchk9zg1HmUZAqdf29KpStXF-75zn0chK4puaeE0QfTFClhjO5O0IhKRhJJCDtFI5IXWSIymZ6jixDWhNCI5yOkF74zEEJV1oB1a_HqG3yj63rAy17vm1PoITKDqSuDF109NOADdp3HSzBda5O5t-DxZ9fWVQva4_mmr4yuo39rKwiX6MzpOsDVXx2jr8nL6nmazOavb8-Ps0RzJvrECgI2d5kthASTlZwLzai21BaE5qmVnFMbFShoxqCwxJm0NMJlrsxTyoGP0d1hrvFdCB6c2viq0X5QlKh9NuqYTWRvDuxGh3iq87o1VTgamCSpYCJiyQGrQg-7o6z9j0oznkm1WiwVncmndznJ1Ufkbw-8NkGtu61v48P_rP8Fe1SAJw</recordid><startdate>19961114</startdate><enddate>19961114</enddate><creator>Liang, Zhiyong</creator><creator>Yang, Zhixin</creator><creator>Sun, Shajing</creator><creator>Wu, Bo</creator><creator>Dalton, Larry R</creator><creator>Garner, Sean M</creator><creator>Kalluri, Srinath</creator><creator>Chen, Antao</creator><creator>Steier, William H</creator><general>American Chemical Society</general><scope>BSCLL</scope><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>19961114</creationdate><title>Processible and Thermally Stable Heterocyclic Polymers for Second-Order Nonlinear Optical Studies</title><author>Liang, Zhiyong ; Yang, Zhixin ; Sun, Shajing ; Wu, Bo ; Dalton, Larry R ; Garner, Sean M ; Kalluri, Srinath ; Chen, Antao ; Steier, William H</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a324t-d40ed8f7d945ec7b334a21ad1d90186d5331d5ece9172e9d0fc6bc4f7fb8613e3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1996</creationdate><topic>Applied sciences</topic><topic>Electrical, magnetic and optical properties</topic><topic>Exact sciences and technology</topic><topic>Organic polymers</topic><topic>Physicochemistry of polymers</topic><topic>Properties and characterization</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Liang, Zhiyong</creatorcontrib><creatorcontrib>Yang, Zhixin</creatorcontrib><creatorcontrib>Sun, Shajing</creatorcontrib><creatorcontrib>Wu, Bo</creatorcontrib><creatorcontrib>Dalton, Larry R</creatorcontrib><creatorcontrib>Garner, Sean M</creatorcontrib><creatorcontrib>Kalluri, Srinath</creatorcontrib><creatorcontrib>Chen, Antao</creatorcontrib><creatorcontrib>Steier, William H</creatorcontrib><collection>Istex</collection><collection>Pascal-Francis</collection><collection>CrossRef</collection><jtitle>Chemistry of materials</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Liang, Zhiyong</au><au>Yang, Zhixin</au><au>Sun, Shajing</au><au>Wu, Bo</au><au>Dalton, Larry R</au><au>Garner, Sean M</au><au>Kalluri, Srinath</au><au>Chen, Antao</au><au>Steier, William H</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Processible and Thermally Stable Heterocyclic Polymers for Second-Order Nonlinear Optical Studies</atitle><jtitle>Chemistry of materials</jtitle><addtitle>Chem. Mater</addtitle><date>1996-11-14</date><risdate>1996</risdate><volume>8</volume><issue>11</issue><spage>2681</spage><epage>2685</epage><pages>2681-2685</pages><issn>0897-4756</issn><eissn>1520-5002</eissn><abstract>Following up on our preliminary communication, we present in this paper a novel approach to synthesize processible, cross-linkable, and thermally stable heterocyclic polymers (polyoxazolidones) with nonlinear optical properties. A cross-linkable NLO chromophore was synthesized and transformed into a prepolymer, which was easy to process and cross-link. After being efficiently poled and cured, the optical-quality films exhibited good nonlinearity and thermal stability. The stable, hardened lattice resulted from the formation of the heterocyclic ring. The details of synthesizing the cross-linked (trifunctional) and un-cross-linked (difunctional) heterocyclic polymers are presented. The effects of the processing conditions on the NLO properties are described. d 33 coefficients of 77 and 85 pm/V at the 1.06 μm fundamental wavelength for the cross-linked and un-cross-linked polymers were obtained, respectively.</abstract><cop>Washington, DC</cop><pub>American Chemical Society</pub><doi>10.1021/cm960221x</doi><tpages>5</tpages></addata></record> |
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| ispartof | Chemistry of materials, 1996-11, Vol.8 (11), p.2681-2685 |
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| language | eng |
| recordid | cdi_crossref_primary_10_1021_cm960221x |
| source | ACS Publications |
| subjects | Applied sciences Electrical, magnetic and optical properties Exact sciences and technology Organic polymers Physicochemistry of polymers Properties and characterization |
| title | Processible and Thermally Stable Heterocyclic Polymers for Second-Order Nonlinear Optical Studies |
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