Microstructure of Laser-Fired, Sol−Gel-Derived Tungsten Oxide Films
Half-micron-thick tungsten oxide films were deposited by the sol−gel method onto indium tin oxide (ITO) coated soda lime silicate substrates. Following a 100 °C prebake, the samples were fired with a carbon dioxide laser at a variety of power densities and translation speeds. The laser-fired tungste...
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| Veröffentlicht in: | Chemistry of Materials 1996-07, Vol.8 (7), p.1396-1401 |
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| container_title | Chemistry of Materials |
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| creator | Taylor, D. J Cronin, J. P Allard, L. F Birnie, D. P |
| description | Half-micron-thick tungsten oxide films were deposited by the sol−gel method onto indium tin oxide (ITO) coated soda lime silicate substrates. Following a 100 °C prebake, the samples were fired with a carbon dioxide laser at a variety of power densities and translation speeds. The laser-fired tungsten oxide films were characterized by spectrophotometry, electrochemistry, multiangle ellipsometry, and transmission electron microscopy and compared to similar furnace-fired films. The data showed an increase in electrochromic response with increased firing temperature up to the point where crystallization of the tungsten oxide retarded electrochromic response. A window with graded electrochromic properties was made by laser firing. |
| doi_str_mv | 10.1021/cm950570b |
| format | Article |
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A window with graded electrochromic properties was made by laser firing.</description><identifier>ISSN: 0897-4756</identifier><identifier>EISSN: 1520-5002</identifier><identifier>DOI: 10.1021/cm950570b</identifier><language>eng</language><publisher>Washington, DC: American Chemical Society</publisher><subject>Condensed matter: structure, mechanical and thermal properties ; CRYSTALLIZATION ; Exact sciences and technology ; MATERIALS SCIENCE ; MICROSTRUCTURE ; Physics ; SOL-GEL PROCESS ; Structure and morphology; thickness ; Surfaces and interfaces; thin films and whiskers (structure and nonelectronic properties) ; TEMPERATURE DEPENDENCE ; Thin film structure and morphology ; TRANSMISSION ELECTRON MICROSCOPY ; TUNGSTEN OXIDES</subject><ispartof>Chemistry of Materials, 1996-07, Vol.8 (7), p.1396-1401</ispartof><rights>Copyright © 1996 American Chemical Society</rights><rights>1996 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-a350t-dbb44aa6a6595a88502393b8af7491fbb736c114742ae438b25bc16811660c473</citedby><cites>FETCH-LOGICAL-a350t-dbb44aa6a6595a88502393b8af7491fbb736c114742ae438b25bc16811660c473</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://pubs.acs.org/doi/pdf/10.1021/cm950570b$$EPDF$$P50$$Gacs$$H</linktopdf><linktohtml>$$Uhttps://pubs.acs.org/doi/10.1021/cm950570b$$EHTML$$P50$$Gacs$$H</linktohtml><link.rule.ids>314,776,780,881,2752,27053,27901,27902,56713,56763</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=3159720$$DView record in Pascal Francis$$Hfree_for_read</backlink><backlink>$$Uhttps://www.osti.gov/biblio/563450$$D View this record in Osti.gov$$Hfree_for_read</backlink></links><search><creatorcontrib>Taylor, D. J</creatorcontrib><creatorcontrib>Cronin, J. P</creatorcontrib><creatorcontrib>Allard, L. F</creatorcontrib><creatorcontrib>Birnie, D. P</creatorcontrib><title>Microstructure of Laser-Fired, Sol−Gel-Derived Tungsten Oxide Films</title><title>Chemistry of Materials</title><addtitle>Chem. Mater</addtitle><description>Half-micron-thick tungsten oxide films were deposited by the sol−gel method onto indium tin oxide (ITO) coated soda lime silicate substrates. Following a 100 °C prebake, the samples were fired with a carbon dioxide laser at a variety of power densities and translation speeds. The laser-fired tungsten oxide films were characterized by spectrophotometry, electrochemistry, multiangle ellipsometry, and transmission electron microscopy and compared to similar furnace-fired films. The data showed an increase in electrochromic response with increased firing temperature up to the point where crystallization of the tungsten oxide retarded electrochromic response. A window with graded electrochromic properties was made by laser firing.</description><subject>Condensed matter: structure, mechanical and thermal properties</subject><subject>CRYSTALLIZATION</subject><subject>Exact sciences and technology</subject><subject>MATERIALS SCIENCE</subject><subject>MICROSTRUCTURE</subject><subject>Physics</subject><subject>SOL-GEL PROCESS</subject><subject>Structure and morphology; thickness</subject><subject>Surfaces and interfaces; thin films and whiskers (structure and nonelectronic properties)</subject><subject>TEMPERATURE DEPENDENCE</subject><subject>Thin film structure and morphology</subject><subject>TRANSMISSION ELECTRON MICROSCOPY</subject><subject>TUNGSTEN OXIDES</subject><issn>0897-4756</issn><issn>1520-5002</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1996</creationdate><recordtype>article</recordtype><recordid>eNpt0L1OwzAQB3ALgUQpDLxBkGBAwmDHnxlRaQuiqKAWVstxHHBJk8pOUHkDZh6RJyFVUCcmD_e7O98fgGOMLjGK8ZVZJgwxgdId0MMsRpAhFO-CHpKJgFQwvg8OQlgghFsue2D44IyvQu0bUzfeRlUeTXSwHo6ct9lFNKuKn6_vsS3gjfXuw2bRvClfQ23LaLp2mY1GrliGQ7CX6yLYo7-3D55Hw_ngFk6m47vB9QRqwlANszSlVGuuOUuYlpKhmCQklToXNMF5mgrCDcZU0FhbSmQas9RgLjHmHBkqSB-cdHPbHzsVjKuteTNVWVpTK8YJZag1553Z3BW8zdXKu6X2nwojtclIbTNq7WlnVzoYXeRel8aFbQPBLBHxZiTsmGsPX2_L2r8rLohgav44U_hFkuSJSnXf-rPOaxPUomp82Ybyz_pfPfx_zw</recordid><startdate>19960711</startdate><enddate>19960711</enddate><creator>Taylor, D. 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P</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a350t-dbb44aa6a6595a88502393b8af7491fbb736c114742ae438b25bc16811660c473</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1996</creationdate><topic>Condensed matter: structure, mechanical and thermal properties</topic><topic>CRYSTALLIZATION</topic><topic>Exact sciences and technology</topic><topic>MATERIALS SCIENCE</topic><topic>MICROSTRUCTURE</topic><topic>Physics</topic><topic>SOL-GEL PROCESS</topic><topic>Structure and morphology; thickness</topic><topic>Surfaces and interfaces; thin films and whiskers (structure and nonelectronic properties)</topic><topic>TEMPERATURE DEPENDENCE</topic><topic>Thin film structure and morphology</topic><topic>TRANSMISSION ELECTRON MICROSCOPY</topic><topic>TUNGSTEN OXIDES</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Taylor, D. J</creatorcontrib><creatorcontrib>Cronin, J. P</creatorcontrib><creatorcontrib>Allard, L. F</creatorcontrib><creatorcontrib>Birnie, D. P</creatorcontrib><collection>Istex</collection><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>OSTI.GOV</collection><jtitle>Chemistry of Materials</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Taylor, D. J</au><au>Cronin, J. P</au><au>Allard, L. F</au><au>Birnie, D. P</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Microstructure of Laser-Fired, Sol−Gel-Derived Tungsten Oxide Films</atitle><jtitle>Chemistry of Materials</jtitle><addtitle>Chem. Mater</addtitle><date>1996-07-11</date><risdate>1996</risdate><volume>8</volume><issue>7</issue><spage>1396</spage><epage>1401</epage><pages>1396-1401</pages><issn>0897-4756</issn><eissn>1520-5002</eissn><abstract>Half-micron-thick tungsten oxide films were deposited by the sol−gel method onto indium tin oxide (ITO) coated soda lime silicate substrates. Following a 100 °C prebake, the samples were fired with a carbon dioxide laser at a variety of power densities and translation speeds. The laser-fired tungsten oxide films were characterized by spectrophotometry, electrochemistry, multiangle ellipsometry, and transmission electron microscopy and compared to similar furnace-fired films. The data showed an increase in electrochromic response with increased firing temperature up to the point where crystallization of the tungsten oxide retarded electrochromic response. A window with graded electrochromic properties was made by laser firing.</abstract><cop>Washington, DC</cop><pub>American Chemical Society</pub><doi>10.1021/cm950570b</doi><tpages>6</tpages></addata></record> |
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| ispartof | Chemistry of Materials, 1996-07, Vol.8 (7), p.1396-1401 |
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| source | American Chemical Society Journals |
| subjects | Condensed matter: structure, mechanical and thermal properties CRYSTALLIZATION Exact sciences and technology MATERIALS SCIENCE MICROSTRUCTURE Physics SOL-GEL PROCESS Structure and morphology thickness Surfaces and interfaces thin films and whiskers (structure and nonelectronic properties) TEMPERATURE DEPENDENCE Thin film structure and morphology TRANSMISSION ELECTRON MICROSCOPY TUNGSTEN OXIDES |
| title | Microstructure of Laser-Fired, Sol−Gel-Derived Tungsten Oxide Films |
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